Half-Sandwich Indenyl Rare Earth Metal Dialkyl Complexes: Syntheses, Structures, and Catalytic Activities of (1,3-(SiMe3)(2)C9H5)Ln(CH2SiMe3)(2)(THF)
文献类型：期刊论文
| 作者 | Xu X(徐信) ; Chen YF(陈耀峰) ; Feng J(冯健) ; Zou G(邹刚) ; Sun J(孙杰) |
| 刊名 | Organometallics
 |
| 出版日期 | 2010 |
| 卷号 | 29期号:3页码:549-553 |
| ISSN号 | 0276-7333 |
| 其他题名 | 单茚基稀土金属双烷基化合物: (1,3-(SiMe3)2C9H5)Ln(CH2SiMe3)2(THF)的合成, 结构及催化活性 |
| 通讯作者 | 陈耀峰 |
| 英文摘要 | Reactions of 1,3-bis(trimethylsilyl)indene with Ln(CH2SiMe3)(3)(THF)(2) gave half-sandwich rare earth metal complexes (1,3-(SiMe3)(2)C9H5)Ln(CH2SiMe3)(2)(THF) (Ln = Y, Lu, Dy). These complexes were characterized by single-crystal X-ray diffraction, which showed the eta(5) hapticity of indenyl ligands in all of the complexes. The catalytic behaviors of the complexes for intramolecular hydroamination of aminoalkenes were investigated. The catalytic activity increased with increasing the metal ion size. and the Y and Dy complexes showed excellent activities to a variety aminoalkenes. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/om900758y |
| 语种 | 英语 |
| WOS记录号 | WOS:000274015800009 |
| 公开日期 | 2013-02-27 |
| 源URL | [http://202.127.28.38/handle/331003/21433]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Xu X,Chen YF,Feng J,et al. Half-Sandwich Indenyl Rare Earth Metal Dialkyl Complexes: Syntheses, Structures, and Catalytic Activities of (1,3-(SiMe3)(2)C9H5)Ln(CH2SiMe3)(2)(THF)[J]. Organometallics,2010,29(3):549-553. |
| APA | 徐信,陈耀峰,冯健,邹刚,&孙杰.(2010).Half-Sandwich Indenyl Rare Earth Metal Dialkyl Complexes: Syntheses, Structures, and Catalytic Activities of (1,3-(SiMe3)(2)C9H5)Ln(CH2SiMe3)(2)(THF).Organometallics,29(3),549-553. |
| MLA | 徐信,et al."Half-Sandwich Indenyl Rare Earth Metal Dialkyl Complexes: Syntheses, Structures, and Catalytic Activities of (1,3-(SiMe3)(2)C9H5)Ln(CH2SiMe3)(2)(THF)".Organometallics 29.3(2010):549-553. |
入库方式： OAI收割
来源：上海有机化学研究所
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