A novel Suzuki-type cross-coupling reaction of cyclopropylboronic esters with benzyl bromides
文献类型：期刊论文
| 作者 | Chen H(陈寒) ; Deng MZ(邓敏智) |
| 刊名 | J. Chem. Soc.-Perkin Trans. 1
 |
| 出版日期 | 2000 |
| 期号 | 10页码:1609-1613 |
| ISSN号 | 1472-7781 |
| 其他题名 | 一个新奇的环丙基硼酸酯与苄溴的Suzuki类型交叉偶亮反应 |
| 通讯作者 | 邓敏智 |
| 英文摘要 | The Suzuki-type coupling reaction of cyclopropylboronic acids (esters) with benzyl bromides readily takes place by using Ag^2O with KOH as the base. The reaction rate and the cross-coupling product yields of cyclopropylbbroMte esters of ethylene glycol or propane-1,3-diol were higher and better than those of cyclopropylfloronic acids. However, the cohpling reaction of the cyclopropylboronate esters of glycol with larger substituents was sluggish. The highly optically active benzyl-substituted cyclopropanes could be obtained by the coupling reactions of corrp.ppnding optically active cyclopropylboronate esters with benzyl bromides. A novel, ideal method fat preparing stereo-defined benzyl-substituted cyclopropanes, especially optically active benryl-substituted cyclopropanes, is described here. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1039/b000121j |
| 语种 | 英语 |
| WOS记录号 | WOS:000087318600019 |
| 公开日期 | 2013-03-07 |
| 源URL | [http://202.127.28.38/handle/331003/23086]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Chen H,Deng MZ. A novel Suzuki-type cross-coupling reaction of cyclopropylboronic esters with benzyl bromides[J]. J. Chem. Soc.-Perkin Trans. 1,2000(10):1609-1613. |
| APA | 陈寒,&邓敏智.(2000).A novel Suzuki-type cross-coupling reaction of cyclopropylboronic esters with benzyl bromides.J. Chem. Soc.-Perkin Trans. 1(10),1609-1613. |
| MLA | 陈寒,et al."A novel Suzuki-type cross-coupling reaction of cyclopropylboronic esters with benzyl bromides".J. Chem. Soc.-Perkin Trans. 1 .10(2000):1609-1613. |
入库方式： OAI收割
来源：上海有机化学研究所
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