Coupling reaction of organoboronic acids with chloropyrimidines and trichlorotriazine
文献类型：期刊论文
| 作者 | Tan JQ(谭久青) ; Chang JH(常建华) ; Deng MZ(邓敏智) |
| 刊名 | Chin. J. Chem.
 |
| 出版日期 | 2004 |
| 卷号 | 22期号:9页码:941-944 |
| ISSN号 | 1001-604X |
| 其他题名 | 氯代嘧啶以及三氯三嗪与有机硼酸的偶联反应 |
| 通讯作者 | 邓敏智 |
| 英文摘要 | Pd-catalyzed cross-coupling reactions of chloropyrimidines with alkenylboronic acids readily proceed to give the corresponding alkenylpyrimidines in high to excellent yields. The coupling reaction of 2,4-dichloropyrimidine or 2,4,6-trichloropyrimidine with one equivalent of alkenylboronic acid occurred more easily on 4-position than on 2-position, which implied that the reaction is highly regioselective. The reaction is stereospecific since the configuration of C=C remained intact. The preliminary study on the cross-coupling reactions of 2,4,6-trichlorotriazine with one equivalent of arylboronic acids showed that the reactions afforded the monosubstituted triazines in moderate yields. The effect of steric hindrance of the substitutents on the reactions was found. |
| 学科主题 | 有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/cjoc.20040220913 |
| 语种 | 英语 |
| WOS记录号 | WOS:000223842000013 |
| 公开日期 | 2013-03-07 |
| 源URL | [http://202.127.28.38/handle/331003/23116]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Tan JQ,Chang JH,Deng MZ. Coupling reaction of organoboronic acids with chloropyrimidines and trichlorotriazine[J]. Chin. J. Chem.,2004,22(9):941-944. |
| APA | 谭久青,常建华,&邓敏智.(2004).Coupling reaction of organoboronic acids with chloropyrimidines and trichlorotriazine.Chin. J. Chem.,22(9),941-944. |
| MLA | 谭久青,et al."Coupling reaction of organoboronic acids with chloropyrimidines and trichlorotriazine".Chin. J. Chem. 22.9(2004):941-944. |
入库方式： OAI收割
来源：上海有机化学研究所
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