Palladium-catalyzed cross-coupling of stereospecific potassium cyclopropyl trifluoroborates with aryl bromides
文献类型：期刊论文
| 作者 | Fang GH(方国华) ; Yan ZJ(严政军) ; Deng MZ(邓敏智) |
| 刊名 | Org. Lett.
 |
| 出版日期 | 2004 |
| 卷号 | 6期号:3页码:357-360 |
| ISSN号 | 1523-7060 |
| 其他题名 | 立体专一的环丙基氟硼酸盐与溴代芳烃的钯催化偶联反应 |
| 通讯作者 | 邓敏智 |
| 英文摘要 | Stereospecific cyclopropanation of alkenylboronic esters of pinacol followed by in situ treatment with excess KHF2 afforded the corresponding potassium cyclopropyl trifluoroborates in high yields, which then underwent Suzuki-Miyaura cross-coupling reactions with aryl bromides to give cyclopropyl-substituted arenes in good yields with retention of configuration. This promises to be a useful method for the synthesis of enantiomerically pure cyclopropanes. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/ol036184e |
| 语种 | 英语 |
| WOS记录号 | WOS:000188596200013 |
| 公开日期 | 2013-03-07 |
| 源URL | [http://202.127.28.38/handle/331003/23120]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Fang GH,Yan ZJ,Deng MZ. Palladium-catalyzed cross-coupling of stereospecific potassium cyclopropyl trifluoroborates with aryl bromides[J]. Org. Lett.,2004,6(3):357-360. |
| APA | 方国华,严政军,&邓敏智.(2004).Palladium-catalyzed cross-coupling of stereospecific potassium cyclopropyl trifluoroborates with aryl bromides.Org. Lett.,6(3),357-360. |
| MLA | 方国华,et al."Palladium-catalyzed cross-coupling of stereospecific potassium cyclopropyl trifluoroborates with aryl bromides".Org. Lett. 6.3(2004):357-360. |
入库方式： OAI收割
来源：上海有机化学研究所
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