Gold-Catalyzed Deacylative Cycloisomerization Reactions of 3-Acylindole/ynes: A New Approach for Carbazole Synthesis
文献类型：期刊论文
| 作者 | Wang L(王璐) ; Li GJ(李贵杰) ; Liu YH(刘元红) |
| 刊名 | Org. Lett.
 |
| 出版日期 | 2011 |
| 卷号 | 13期号:15页码:3786-3789 |
| ISSN号 | 1523-7060 |
| 其他题名 | 金催化的3-酰基吲哚的环化去酰化反应: 咔唑化合物的新合成法研究 |
| 通讯作者 | 刘元红 |
| 英文摘要 | The synthesis of functionalized carbazoles through gold-catalyzed deacylative cycloisomerization of 3-acylindole/ynes is described. A mechanistic proposal for these transformations involving a novel carbonyl group facilitated heterolytic fragmentation upon the loss of an acylium ion intermediate is presented. The eliminated acylium ion species could be trapped by the organogold intermediate to afford acylcarbazoles. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/ol2012154 |
| 语种 | 英语 |
| WOS记录号 | WOS:000293252800005 |
| 公开日期 | 2013-03-11 |
| 源URL | [http://202.127.28.38/handle/331003/24307]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Wang L,Li GJ,Liu YH. Gold-Catalyzed Deacylative Cycloisomerization Reactions of 3-Acylindole/ynes: A New Approach for Carbazole Synthesis[J]. Org. Lett.,2011,13(15):3786-3789. |
| APA | 王璐,李贵杰,&刘元红.(2011).Gold-Catalyzed Deacylative Cycloisomerization Reactions of 3-Acylindole/ynes: A New Approach for Carbazole Synthesis.Org. Lett.,13(15),3786-3789. |
| MLA | 王璐,et al."Gold-Catalyzed Deacylative Cycloisomerization Reactions of 3-Acylindole/ynes: A New Approach for Carbazole Synthesis".Org. Lett. 13.15(2011):3786-3789. |
入库方式： OAI收割
来源：上海有机化学研究所
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