Synthesis of amphiphilic graft copolymer with hydrophilic poly(acrylic acid) backbone and hydrophobic polystyrene side chains
文献类型：期刊论文
| 作者 | Peng D(彭丹) ; Zhang XH(张晓环) ; Huang XY(黄晓宇) |
| 刊名 | Polymer
 |
| 出版日期 | 2006 |
| 卷号 | 47期号:17页码:6072-6080 |
| ISSN号 | 0032-3861 |
| 其他题名 | 含有亲水聚丙烯酸主链和憎水聚苯乙烯侧链的两亲性接枝共聚物的合成 |
| 通讯作者 | 黄晓宇 |
| 英文摘要 | A series of well-defined amphiphilic graft copolymers consisting hydrophilic poly(acrylic acid) backbones and hydrophobic polystyrene side chains were synthesized by successive atom transfer radical polymerization (ATRP) followed by hydrolysis of poly(methoxymethyl acrylate) (PMOMA) backbone. Grafting-from strategy was employed for the synthesis of graft copolymers with narrow molecular weight distribution. Hydrophobic side chains were connected to the backbone through stable C-C bonds. The backbone can be easily hydrolyzed with HCl without affecting hydrophobic side chains. This family of amphiphilic graft copolymers can form stable micelles in water. The critical micelle concentration was determined by fluorescence spectroscopy. The micellar morphologies and sizes were studied using transmission electron microscopy (TEM) and dynamic light scattering (DLS). The sizes of micelles were dependent on ionic strength, pH value and preparation conditions. (c) 2006 Elsevier Ltd. All rights reserved. |
| 学科主题 | 高分子化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1016/j.polymer.2006.06.045 |
| 语种 | 英语 |
| WOS记录号 | WOS:000239973500008 |
| 公开日期 | 2013-03-11 |
| 源URL | [http://202.127.28.38/handle/331003/24365]  |
| 专题 | 上海有机化学研究所_高分子材料研究室 |
| 推荐引用方式 GB/T 7714 | Peng D,Zhang XH,Huang XY. Synthesis of amphiphilic graft copolymer with hydrophilic poly(acrylic acid) backbone and hydrophobic polystyrene side chains[J]. Polymer,2006,47(17):6072-6080. |
| APA | 彭丹,张晓环,&黄晓宇.(2006).Synthesis of amphiphilic graft copolymer with hydrophilic poly(acrylic acid) backbone and hydrophobic polystyrene side chains.Polymer,47(17),6072-6080. |
| MLA | 彭丹,et al."Synthesis of amphiphilic graft copolymer with hydrophilic poly(acrylic acid) backbone and hydrophobic polystyrene side chains".Polymer 47.17(2006):6072-6080. |
入库方式： OAI收割
来源：上海有机化学研究所
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