Synthesis of polyallene-based graft copolymer via 6-methyl-1,2-heptadien-4-ol and styrene
文献类型：期刊论文
| 作者 | Zhang XH(张晓环) ; Shen Z(沈重) ; Li LT(李利涛) ; Zhang S(张森) ; Lu GL(陆国林) ; Huang XY(黄晓宇) |
| 刊名 | J. Polym. Sci. Pol. Chem.
 |
| 出版日期 | 2007 |
| 卷号 | 45期号:23页码:5509-5517 |
| ISSN号 | 0887-624X |
| 其他题名 | 以6-甲基-1,2-庚二烯-4-醇和苯乙烯为单体合成聚联烯主链的接枝共聚物 |
| 通讯作者 | 黄晓宇 |
| 英文摘要 | A series of well-defined graft copolymers with a polyallene-based backbone and polystyrene side chains were synthesized by the combination of living coordination polymerization of 6-methyl-1,2-heptadien-4-ol and atom transfer radical polymerization (ATRP) of styrene. Poly(alcohol) with polyallene repeating units were prepared via 6-methyl-1,2-heptadien-4-ol by living coordination polymerization initiated by [(eta(3)-allyl)NiOCOCF3](2) firstly, followed by transforming the pendant hydroxyl groups into halogen-containing ATRP initiation groups. Grafting-from route was employed in the following step for the synthesis of the well-defined graft copolymer: polystyrene was grafted to the backbone via ATRP of styrene. The cleaved polystyrene side chains show a narrow molecular weight distribution (M-w/M-n = 1.06). This kind of graft copolymer is the first example of graft copolymer via allene derivative and styrenic monomer. ? 2007 Wiley Periodicals, Inc. |
| 学科主题 | 高分子化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/pola.22296 |
| 语种 | 英语 |
| WOS记录号 | WOS:000251631100014 |
| 公开日期 | 2013-03-11 |
| 源URL | [http://202.127.28.38/handle/331003/24383]  |
| 专题 | 上海有机化学研究所_高分子材料研究室 |
| 推荐引用方式 GB/T 7714 | Zhang XH,Shen Z,Li LT,et al. Synthesis of polyallene-based graft copolymer via 6-methyl-1,2-heptadien-4-ol and styrene[J]. J. Polym. Sci. Pol. Chem.,2007,45(23):5509-5517. |
| APA | 张晓环,沈重,李利涛,张森,陆国林,&黄晓宇.(2007).Synthesis of polyallene-based graft copolymer via 6-methyl-1,2-heptadien-4-ol and styrene.J. Polym. Sci. Pol. Chem.,45(23),5509-5517. |
| MLA | 张晓环,et al."Synthesis of polyallene-based graft copolymer via 6-methyl-1,2-heptadien-4-ol and styrene".J. Polym. Sci. Pol. Chem. 45.23(2007):5509-5517. |
入库方式： OAI收割
来源：上海有机化学研究所
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