PMHDO-g-PEG Double-Bond-Based Amphiphilic Graft Copolymer: Synthesis and Diverse Self-Assembled Nanostructures
文献类型：期刊论文
| 作者 | Zhang XH(张晓环) ; Shen Z(沈重) ; Feng C(冯纯) ; Yang D(杨东) ; Li YG(李垚功) ; Hu JH(胡建华) ; Lu GL(陆国林) ; Huang XY(黄晓宇) |
| 刊名 | Macromolecules
 |
| 出版日期 | 2009 |
| 卷号 | 42期号:12页码:4249-4256 |
| ISSN号 | 0024-9297 |
| 其他题名 | 含有双键结构的PMHDO-g-PEG两亲性接枝共聚物的合成及多种自组装纳米结构的研究 |
| 通讯作者 | 胡建华 ; 黄晓宇 |
| 英文摘要 | Self-assembly behavior of a double-bond-based amphiphilic graft copolymer consisting of hydrophobic polyallene backbone and hydrophilic poly(ethylene glycol) side chains in tetrahydrofuran (THF)/water was investigated. Polyallene backbone was first prepared via living coordination polymerization of 6-methyl-1,2-heptadien-4-ol (MHDO) initiated by [(eta(3)-allyl)NiOCOCF3](2). The targeted amphiphilic graft copolymer with relative narrow molecular weight distribution (M-w/M-n = 1.22) was synthesized by the coupling reaction between the pendant hydroxyls of the backbone and acyl chloride end group of poly (ethylene glycol) via the grafting-onto approach. The critical micelle concentration (cmc) was determined by the fluorescence probe technique. Micelle morphologies could be well tuned by water content, initial copolymer content, and ion strength. In particular, this kind of achiral copolymer could aggregate to form chiral helical nanostructures under given conditions. |
| 学科主题 | 高分子化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/ma900343z |
| 语种 | 英语 |
| WOS记录号 | WOS:000267048200061 |
| 公开日期 | 2013-03-11 |
| 源URL | [http://202.127.28.38/handle/331003/24405]  |
| 专题 | 上海有机化学研究所_高分子材料研究室 |
| 推荐引用方式 GB/T 7714 | Zhang XH,Shen Z,Feng C,et al. PMHDO-g-PEG Double-Bond-Based Amphiphilic Graft Copolymer: Synthesis and Diverse Self-Assembled Nanostructures[J]. Macromolecules,2009,42(12):4249-4256. |
| APA | 张晓环.,沈重.,冯纯.,杨东.,李垚功.,...&黄晓宇.(2009).PMHDO-g-PEG Double-Bond-Based Amphiphilic Graft Copolymer: Synthesis and Diverse Self-Assembled Nanostructures.Macromolecules,42(12),4249-4256. |
| MLA | 张晓环,et al."PMHDO-g-PEG Double-Bond-Based Amphiphilic Graft Copolymer: Synthesis and Diverse Self-Assembled Nanostructures".Macromolecules 42.12(2009):4249-4256. |
入库方式： OAI收割
来源：上海有机化学研究所
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