Molecularly imprinted matrix solid-phase dispersion coupled to micellar electrokinetic chromatography for simultaneous determination of triazines in soil, fruit, and vegetable samples
文献类型：期刊论文
| 作者 | Wen, Yingying1,4; Chen, Lingxin1 ; Li, Jinhua1; Ma, Yanling1,3; Xu, Shoufang1,4; Zhang, Zhong1; Niu, Zongliang1; Choo, Jaebum2
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| 刊名 | ELECTROPHORESIS
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| 出版日期 | 2012-08-01 |
| 卷号 | 33期号:15页码:2454-2463 |
| 关键词 | Matrix solid-phase dispersion Micellar electrokinetic chromatography Molecularly imprinted polymers Orthogonal design Triazines |
| ISSN号 | 0173-0835 |
| 产权排序 | [Wen, Yingying; Chen, Lingxin; Li, Jinhua; Ma, Yanling; Xu, Shoufang; Zhang, Zhong; Niu, Zongliang] Chinese Acad Sci, Key Lab Coastal Zone Environm Proc, Shandong Prov Key Lab Coastal Zone Environm Proc, Yantai Inst Coastal Zone Res YIC,YICCAS, Yantai 264003, Peoples R China; [Choo, Jaebum] Hanyang Univ, Dept Bionano Engn, Ansan, South Korea; [Ma, Yanling] Qufu Normal Univ, Coll Chem & Chem Engn, Qufu, Peoples R China; [Wen, Yingying; Xu, Shoufang] Chinese Acad Sci, Grad Univ, Beijing, Peoples R China |
| 通讯作者 | Chen, LX (reprint author), Chinese Acad Sci, Key Lab Coastal Zone Environm Proc, Shandong Prov Key Lab Coastal Zone Environm Proc, Yantai Inst Coastal Zone Res YIC,YICCAS, Yantai 264003, Peoples R China.,lxchen@yic.ac.cn |
| 中文摘要 | A simple and sensitive method for the simultaneous determination of four triazines from soil, strawberry, and tomato samples was developed by selective molecularly imprinted matrix solid-phase dispersion (MI-MSPD) coupled to micellar electrokinetic chromatography (MEKC). Using atrazine as template, the synthesized molecularly imprinted polymers (MIPs) were employed as the dispersion sorbent of MSPD to successfully extract atrazine and its analogs of simazine, ametryn, and propazine from the three different real samples, while matrix interferences were effectively eliminated simultaneously under the optimum extraction conditions. Excellent separation was achieved within 7 min by using an optimized buffer system composed of 30 mmol/L ammonium acetate, 20 mmol/L SDS, and 15% ACN at pH 9.45, obtained by orthogonal design. Good linearity was obtained in a range of 0.525 mu g/g with the correlation coefficients R2 =0.9991 except for strawberry sample within 125 mu g/g, and limits of detection were between 12.931.5 ng/g in all the three samples. The average recoveries of the four triazines at three different spiked levels were ranged from 53.5 to 98.4% with the relative standard deviations of 1.284.89%. This method was proved convenient, costeffective, and environmental benign and could be used as an alternative tool to the existing methods for analyzing the residues of triazines in soil, fruit, and vegetable samples. |
| 英文摘要 | A simple and sensitive method for the simultaneous determination of four triazines from soil, strawberry, and tomato samples was developed by selective molecularly imprinted matrix solid-phase dispersion (MI-MSPD) coupled to micellar electrokinetic chromatography (MEKC). Using atrazine as template, the synthesized molecularly imprinted polymers (MIPs) were employed as the dispersion sorbent of MSPD to successfully extract atrazine and its analogs of simazine, ametryn, and propazine from the three different real samples, while matrix interferences were effectively eliminated simultaneously under the optimum extraction conditions. Excellent separation was achieved within 7 min by using an optimized buffer system composed of 30 mmol/L ammonium acetate, 20 mmol/L SDS, and 15% ACN at pH 9.45, obtained by orthogonal design. Good linearity was obtained in a range of 0.525 mu g/g with the correlation coefficients R2 =0.9991 except for strawberry sample within 125 mu g/g, and limits of detection were between 12.931.5 ng/g in all the three samples. The average recoveries of the four triazines at three different spiked levels were ranged from 53.5 to 98.4% with the relative standard deviations of 1.284.89%. This method was proved convenient, costeffective, and environmental benign and could be used as an alternative tool to the existing methods for analyzing the residues of triazines in soil, fruit, and vegetable samples. |
| 学科主题 | Biochemical Research Methods; Chemistry, Analytical |
| 研究领域[WOS] | Biochemistry & Molecular Biology ; Chemistry |
| 关键词[WOS] | PERFORMANCE LIQUID-CHROMATOGRAPHY ; ORGANOPHOSPHORUS PESTICIDES ; CAPILLARY-ELECTROPHORESIS ; ENVIRONMENTAL-SAMPLES ; EXTRACTION ; MICROEXTRACTION ; HERBICIDES ; POLYMERS ; RECOGNITION ; DEGRADATION |
| 收录类别 | SCI |
| 资助信息 | National Natural Science Foundation of China[21105117, 20975089]; Innovation Projects of the Chinese Academy of Sciences[KZCX2-EW-206]; National Research Foundation of Korea[R11-2008-0061852, K20904000004-11A0500-00410, K20904000004-10A0500-00410]; Natural Science Foundation of Shandong Province of China[ZR2010BQ027]; Yantai Research and Development Program of China[2010158]; Chinese Academy of Sciences |
| 语种 | 英语 |
| WOS记录号 | WOS:000307399400025 |
| 公开日期 | 2013-03-08 |
| 源URL | [http://ir.yic.ac.cn/handle/133337/6019]  |
| 专题 | 烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Coastal Zone Environm Proc, Shandong Prov Key Lab Coastal Zone Environm Proc, Yantai Inst Coastal Zone Res YIC,YICCAS, Yantai 264003, Peoples R China 2.Hanyang Univ, Dept Bionano Engn, Ansan, South Korea 3.Qufu Normal Univ, Coll Chem & Chem Engn, Qufu, Peoples R China 4.Chinese Acad Sci, Grad Univ, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wen, Yingying,Chen, Lingxin,Li, Jinhua,et al. Molecularly imprinted matrix solid-phase dispersion coupled to micellar electrokinetic chromatography for simultaneous determination of triazines in soil, fruit, and vegetable samples[J]. ELECTROPHORESIS,2012,33(15):2454-2463. |
| APA | Wen, Yingying.,Chen, Lingxin.,Li, Jinhua.,Ma, Yanling.,Xu, Shoufang.,...&Choo, Jaebum.(2012).Molecularly imprinted matrix solid-phase dispersion coupled to micellar electrokinetic chromatography for simultaneous determination of triazines in soil, fruit, and vegetable samples.ELECTROPHORESIS,33(15),2454-2463. |
| MLA | Wen, Yingying,et al."Molecularly imprinted matrix solid-phase dispersion coupled to micellar electrokinetic chromatography for simultaneous determination of triazines in soil, fruit, and vegetable samples".ELECTROPHORESIS 33.15(2012):2454-2463. |
入库方式： OAI收割
来源：烟台海岸带研究所
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