Two Bulky-Decorated Triangular Dysprosium Aggregates Conserving Vortex-Spin Structure
文献类型：期刊论文
| 作者 | Xue SF ; Chen XH ; Zhao L ; Guo YN ; Tang JK |
| 刊名 | inorganic chemistry
 |
| 出版日期 | 2012 |
| 卷号 | 51期号:24页码:13264-13270 |
| 关键词 | SINGLE-MOLECULE-MAGNET SHARING DY-3 TRIANGLES ANISOTROPIC BARRIER GROUND-STATE RELAXATION BEHAVIOR COMPLEXES LIGANDS ORIGIN MOMENT |
| ISSN号 | 0020-1669 |
| 通讯作者 | tang jk |
| 中文摘要 | the self-assembly of dysprosium(iii) with the tailored chemical modification of the vanillin group affords two decorated dy-3 compounds, namely, [dy-3(mu(3)-oh)(2)(hpovh(-))(3)(no3)(3)(ch3oh)(2)-h2o]center dot no3 center dot 3ch(3)oh center dot 2h(2)o (2) and [dy-3(mu(3)-oh)(2)(h(2)vovh(-))(3)cl-2(ch3-oh)(h2o)(3)][dy-3(mu(3)-oh)(2)(h(2)vovh-)(3)cl-2(h2o)(4)]center dot cl-4 center dot 2ch(3)oh center dot 2ch(3)-cn center dot 7h(2)o (3), where h(2)povh = n-(pyridylmethylene)-o-vanilloylhydrazone and h(3)vovh = n-vanillidene-o-vanilloylhydrazone. of particular interest is that those two title dy-3 compounds maintain the peculiar vortex-spin structure of the ground nonmagnetic doublet. complex 2 displays frequency-dependent slow magnetic relaxation, while 3 still inherits the single-molecule-magnet behavior as the parent dy-3 prototype. the dissimilar dynamic magnetic behavior originates from the structural differences in light of the coordination environment of dy-iii ions, which influence the local tensor of anisotropy and crystal-field splitting on each dy site. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000312351800024 |
| 公开日期 | 2013-03-17 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/47788]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Xue SF,Chen XH,Zhao L,et al. Two Bulky-Decorated Triangular Dysprosium Aggregates Conserving Vortex-Spin Structure[J]. inorganic chemistry,2012,51(24):13264-13270. |
| APA | Xue SF,Chen XH,Zhao L,Guo YN,&Tang JK.(2012).Two Bulky-Decorated Triangular Dysprosium Aggregates Conserving Vortex-Spin Structure.inorganic chemistry,51(24),13264-13270. |
| MLA | Xue SF,et al."Two Bulky-Decorated Triangular Dysprosium Aggregates Conserving Vortex-Spin Structure".inorganic chemistry 51.24(2012):13264-13270. |
入库方式： OAI收割
来源：长春应用化学研究所
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