Fine control of titania deposition to prepare C@TiO2 composites and TiO2 hollow particles for photocatalysis and lithium-ion battery applications
文献类型：期刊论文
| 作者 | Ming J ; Wu YQ ; Nagarajan S ; Lee DJ ; Sun YK ; Zhao FY |
| 刊名 | journal of materials chemistry
 |
| 出版日期 | 2012 |
| 卷号 | 22期号:41页码:22135-22141 |
| 关键词 | SENSITIZED SOLAR-CELLS TEXTURAL PROPERTIES ELECTRON INJECTION HIGH-DENSITY RUTILE TIO2 SPHERES OXIDE NANOPARTICLES ANATASE CARBON |
| ISSN号 | 0959-9428 |
| 通讯作者 | sun yk |
| 中文摘要 | in this study, an effective method of slow hydrolization of metal alkoxide (e.g., ti(c4h9o)(4)) in an ethanol-water system was systematically investigated and used to finely control the deposition of titania on carbon colloids. a model of adsorption-hydrolization of precursors during the coating process was rationally built for the first time to interpret the usability of the method and facilitate its further extension. using this strategy, titania in the form of supported nanocrystals or layers on carbon colloids (tio2/c, c@tio2) was successfully tailored. meanwhile, finely dispersed hollow tio2 nanoparticles with shells consisting of different crystalline structures were also prepared by varying the calcination conditions after removing the carbon cores. more importantly, the effects of the crystalline and nano/macrostructures of the as-prepared tio2 samples in photocatalysis and lithium-ion battery applications were analyzed in detail. the preliminary results show that anatase-rutile tio2 hollow particles demonstrate a higher catalytic activity in the photo-degradation of rhodamine b than anatase tio2 hollow particles, powders, and p25. however, in the case of li-ion battery applications, the anatase tio2 hollow particles exhibited better performance as anode materials with high capacities of around 190 ma h(-1), 140 ma h g(-1), and 120 ma h g(-1) at current densities of 60 ma g(-1), 120 ma g(-1) and 300 ma g(-1), respectively, accompanied by stable cyclability. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000310047200049 |
| 公开日期 | 2013-03-18 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/47852]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Ming J,Wu YQ,Nagarajan S,et al. Fine control of titania deposition to prepare C@TiO2 composites and TiO2 hollow particles for photocatalysis and lithium-ion battery applications[J]. journal of materials chemistry,2012,22(41):22135-22141. |
| APA | Ming J,Wu YQ,Nagarajan S,Lee DJ,Sun YK,&Zhao FY.(2012).Fine control of titania deposition to prepare C@TiO2 composites and TiO2 hollow particles for photocatalysis and lithium-ion battery applications.journal of materials chemistry,22(41),22135-22141. |
| MLA | Ming J,et al."Fine control of titania deposition to prepare C@TiO2 composites and TiO2 hollow particles for photocatalysis and lithium-ion battery applications".journal of materials chemistry 22.41(2012):22135-22141. |
入库方式： OAI收割
来源：长春应用化学研究所
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