Construction of Three-Dimensional Cobalt(II)-Based Metal-Organic Frameworks by Synergy between Rigid and Semirigid Ligands
文献类型：期刊论文
| 作者 | Yang WT ; Guo M ; Yi FY ; Sun ZM |
| 刊名 | crystal growth & design
 |
| 出版日期 | 2012 |
| 卷号 | 12期号:11页码:5529-5534 |
| 关键词 | SEPARATION STORAGE INTERPENETRATION TRANSFORMATION RECOGNITION CATENATION ISOMERS |
| ISSN号 | 1528-7483 |
| 通讯作者 | sun zm |
| 中文摘要 | solvothermal assembly of co(ii) ion, a semirigid tetrahedral carboxylate ligand tetrakis[(4-carboxyphenyl)oxamethyl]methane acid (h4l), and rigid linear bidentate linker 1,4-di(1h-imidazol-1-yl)benzene (dib) or 4,4'-di(1h-imidazol-1-yl)-1,1'-biphenyl (dibp) yields four novel metal-organic frameworks (1-4) with different topological connections. [co-2(l)(dib)]center dot 3dmf (1) is a 2-fold interpenetrating sqc422 network and contains 3-dimensional interconnected channels along [100], [010], and [110] directions; [co-4(l)(2)(dib)(3)(h2o)(4)]center dot 4h(2)o (2) is a three-dimensional 3,4,4 connected new topology with 5-fold interpenetration; [co-2(1-)(dibp)]center dot 5dmf (3) and co-2(l)(dibp)2 (4) are formed in the presence of dibp linker; they feature three-dimensional novel topologies based on 4,6 connection and 4,4 connection, respectively, and no interpenetration is observed. it is demonstrated that interpenetration is accessible simply by changing auxiliary ligands and solvents. magnetic studies reveal that complexes 1 and 3 exhibit antiferromagnetic behavior. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000311240100046 |
| 公开日期 | 2013-03-18 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/47860]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Yang WT,Guo M,Yi FY,et al. Construction of Three-Dimensional Cobalt(II)-Based Metal-Organic Frameworks by Synergy between Rigid and Semirigid Ligands[J]. crystal growth & design,2012,12(11):5529-5534. |
| APA | Yang WT,Guo M,Yi FY,&Sun ZM.(2012).Construction of Three-Dimensional Cobalt(II)-Based Metal-Organic Frameworks by Synergy between Rigid and Semirigid Ligands.crystal growth & design,12(11),5529-5534. |
| MLA | Yang WT,et al."Construction of Three-Dimensional Cobalt(II)-Based Metal-Organic Frameworks by Synergy between Rigid and Semirigid Ligands".crystal growth & design 12.11(2012):5529-5534. |
入库方式： OAI收割
来源：长春应用化学研究所
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