Scopariusins, A New Class of ent-Halimane Diterpenoids Isolated from Isodon scoparius, and Biomimetic Synthesis of Scopariusin A and Isoscoparin N
文献类型:期刊论文
作者 | Zhou, Min1,2; Geng, Hui-Chun1,2; Zhang, Hai-Bo1; Dong, Ke1; Wang, Wei-Guang1,2; Du, Xue1; Li, Xiao-Nian1; He, Fei1; Qin, Hong-Bo1![]() ![]() |
刊名 | ORGANIC LETTERS
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出版日期 | 2013-01-18 |
卷号 | 15期号:2页码:314-317 |
关键词 | SKELETON |
ISSN号 | 1523-7060 |
通讯作者 | Pu, JX (reprint author), Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources W China, Kunming 650201, Yunnan, Peoples R China.,pujianxin@mail.kib.ac.cn ; hdsun@mail.kib.ac.cn |
英文摘要 | Scopariusins A-C (1-3), three novel rearranged ent-halimanoids with a bicycle[5.4.0]undecane ring system, two new normal ent-halimanoids (4 and 5), and a new ent-clerodanoid (6) were isolated from Isodon scoparius. Moreover, a biomimetic transformation from the ent-clerodanoid to the normal and the rearranged ent-halimane diterpenoids was successfully accomplished, which not only validated the biogenetic hypothesis in this plant but also confirmed the absolute configurations of 1 and 5. |
WOS标题词 | Science & Technology ; Physical Sciences |
学科主题 | Chemistry |
类目[WOS] | Chemistry, Organic |
研究领域[WOS] | Chemistry |
关键词[WOS] | SKELETON |
收录类别 | SCI ; IC ; CCR |
资助信息 | NSFC-Joint Foundation of Yunnan Province [U0832602]; NSFC [81172939]; reservation-talent project of Yunnan Province [2011CI043]; Major Direction Projection Foundation of CAS Intellectual Innovation Project [KSCX2-EW-J-24] |
语种 | 英语 |
WOS记录号 | WOS:000314007700021 |
公开日期 | 2013-03-18 |
源URL | [http://ir.kib.ac.cn/handle/151853/16204] ![]() |
专题 | 昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室 |
作者单位 | 1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources W China, Kunming 650201, Yunnan, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Zhou, Min,Geng, Hui-Chun,Zhang, Hai-Bo,et al. Scopariusins, A New Class of ent-Halimane Diterpenoids Isolated from Isodon scoparius, and Biomimetic Synthesis of Scopariusin A and Isoscoparin N[J]. ORGANIC LETTERS,2013,15(2):314-317. |
APA | Zhou, Min.,Geng, Hui-Chun.,Zhang, Hai-Bo.,Dong, Ke.,Wang, Wei-Guang.,...&Sun, Han-Dong.(2013).Scopariusins, A New Class of ent-Halimane Diterpenoids Isolated from Isodon scoparius, and Biomimetic Synthesis of Scopariusin A and Isoscoparin N.ORGANIC LETTERS,15(2),314-317. |
MLA | Zhou, Min,et al."Scopariusins, A New Class of ent-Halimane Diterpenoids Isolated from Isodon scoparius, and Biomimetic Synthesis of Scopariusin A and Isoscoparin N".ORGANIC LETTERS 15.2(2013):314-317. |
入库方式: OAI收割
来源:昆明植物研究所
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