中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Scopariusins, A New Class of ent-Halimane Diterpenoids Isolated from Isodon scoparius, and Biomimetic Synthesis of Scopariusin A and Isoscoparin N

文献类型:期刊论文

作者Zhou, Min1,2; Geng, Hui-Chun1,2; Zhang, Hai-Bo1; Dong, Ke1; Wang, Wei-Guang1,2; Du, Xue1; Li, Xiao-Nian1; He, Fei1; Qin, Hong-Bo1; Li, Yan1
刊名ORGANIC LETTERS
出版日期2013-01-18
卷号15期号:2页码:314-317
关键词SKELETON
ISSN号1523-7060
通讯作者Pu, JX (reprint author), Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources W China, Kunming 650201, Yunnan, Peoples R China.,pujianxin@mail.kib.ac.cn ; hdsun@mail.kib.ac.cn
英文摘要Scopariusins A-C (1-3), three novel rearranged ent-halimanoids with a bicycle[5.4.0]undecane ring system, two new normal ent-halimanoids (4 and 5), and a new ent-clerodanoid (6) were isolated from Isodon scoparius. Moreover, a biomimetic transformation from the ent-clerodanoid to the normal and the rearranged ent-halimane diterpenoids was successfully accomplished, which not only validated the biogenetic hypothesis in this plant but also confirmed the absolute configurations of 1 and 5.
WOS标题词Science & Technology ; Physical Sciences
学科主题Chemistry
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]SKELETON
收录类别SCI ; IC ; CCR
资助信息NSFC-Joint Foundation of Yunnan Province [U0832602]; NSFC [81172939]; reservation-talent project of Yunnan Province [2011CI043]; Major Direction Projection Foundation of CAS Intellectual Innovation Project [KSCX2-EW-J-24]
语种英语
WOS记录号WOS:000314007700021
公开日期2013-03-18
源URL[http://ir.kib.ac.cn/handle/151853/16204]  
专题昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室
作者单位1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources W China, Kunming 650201, Yunnan, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Zhou, Min,Geng, Hui-Chun,Zhang, Hai-Bo,et al. Scopariusins, A New Class of ent-Halimane Diterpenoids Isolated from Isodon scoparius, and Biomimetic Synthesis of Scopariusin A and Isoscoparin N[J]. ORGANIC LETTERS,2013,15(2):314-317.
APA Zhou, Min.,Geng, Hui-Chun.,Zhang, Hai-Bo.,Dong, Ke.,Wang, Wei-Guang.,...&Sun, Han-Dong.(2013).Scopariusins, A New Class of ent-Halimane Diterpenoids Isolated from Isodon scoparius, and Biomimetic Synthesis of Scopariusin A and Isoscoparin N.ORGANIC LETTERS,15(2),314-317.
MLA Zhou, Min,et al."Scopariusins, A New Class of ent-Halimane Diterpenoids Isolated from Isodon scoparius, and Biomimetic Synthesis of Scopariusin A and Isoscoparin N".ORGANIC LETTERS 15.2(2013):314-317.

入库方式: OAI收割

来源:昆明植物研究所

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