Electrochemical and photochemical characterization of novel ferrocenyl–azobenzene labeled PNA monomers for DNA detection
文献类型：期刊论文
| 作者 | Li JD(李进都) ; Chen M(陈淼) ; Zhang HB(张浩波) ; Liu S(刘胜) |
| 刊名 | Inorganic Chemistry Communications
 |
| 出版日期 | 2008 |
| 卷号 | 11页码:392-395 |
| 关键词 | Peptide nucleic acid (PNA) Ferrocene Azobenzene Electrochemistry Photochemistry |
| ISSN号 | 1387-7003 |
| 通讯作者 | 陈淼 |
| 中文摘要 | Ferrocenyl–azobenzene carboxylic acid was synthesized and used as electrochemically and spectroscopically active marker that wasconjugated to thymine PNA monomer. Ferrocenyl–azobenzene labeled PNA monomer of thymine (Fc–Azo–T) shows highly electrochemical and photochemical activity. The detection limit of Fc–Azo–T can reach 10 6M by using differential pulsed voltammogram (DPV), and the UV–vis limit is in the order 10 7M in ethanol. Fc–Azo–T can undergo facile isomerization by photoirradiation. The results give great motivity for synthesizing ferrocenyl–azobenzene labeled PNA oligomers used as an effective electrochemical and photochemical probes. |
| 学科主题 | 材料科学与物理化学 |
| 收录类别 | SCI |
| 资助信息 | the National Nature Science Foundation of China (Grant No. 20473106);the Innovation Group Project (Grant No. 50421502);973 Project (Grant No. 2007CB607605) of the Chinese Ministry of Science and Technology |
| 语种 | 英语 |
| 公开日期 | 2013-03-28 |
| 源URL | [http://210.77.64.217/handle/362003/2609]  |
| 专题 | 兰州化学物理研究所_固体润滑国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Li JD,Chen M,Zhang HB,et al. Electrochemical and photochemical characterization of novel ferrocenyl–azobenzene labeled PNA monomers for DNA detection[J]. Inorganic Chemistry Communications,2008,11:392-395. |
| APA | 李进都,陈淼,张浩波,&刘胜.(2008).Electrochemical and photochemical characterization of novel ferrocenyl–azobenzene labeled PNA monomers for DNA detection.Inorganic Chemistry Communications,11,392-395. |
| MLA | 李进都,et al."Electrochemical and photochemical characterization of novel ferrocenyl–azobenzene labeled PNA monomers for DNA detection".Inorganic Chemistry Communications 11(2008):392-395. |
入库方式： OAI收割
来源：兰州化学物理研究所
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