Synthesis and properties of novel poly(benzimidazopyrrolone amide)s containing pyridine moieties
文献类型：期刊论文
| 作者 | Wang XL(王晓龙)
|
| 刊名 | Journal of Applied Polymer Science
 |
| 出版日期 | 2008 |
| 卷号 | 109页码:3369-3375 |
| 关键词 | heteroatom-containing polymers high-performance polymers thermal properties |
| ISSN号 | 0021-8995 |
| 通讯作者 | 李彦峰 |
| 中文摘要 | A series of new poly(benzimidazopyrrolone amide) (PPA) copolymers were synthesized by a two-step procedure, which was the solution polycondensation of a novel pyridine-containing tetraamine with various aromatic dianhydrides at a room temperature and cyclization of the resulting prepolymers at a high temperature, respectively. The resulting prepolymers from the solution polycondensation, that is, poly(amide amino acid)s (PAAAs), had inherent viscosities of 0.82–0.91 dL/g; then, tough and flexible PPA films could be successfully prepared by the casting of the PAAA solutions onto a glass substrate followed by thermal curing with a program temperature procedure up to 350℃. The obtained PPA films exhibited not only excellent thermal properties with onset decomposition temperatures in the range 502–521℃, glass-transition temperatures in the range 299–337℃, and residual weight retentions at 700℃ in air of 29.1–34.8% but also good mechanical properties with tensile strengths of 102.1–115.9 MPa and elongations at break of 6.8–7.4%. |
| 学科主题 | 材料科学与物理化学 |
| 收录类别 | SCI |
| 资助信息 | Research Foundation of the State Key Laboratory of Applied Organic Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000257442900081 |
| 公开日期 | 2013-03-28 |
| 源URL | [http://210.77.64.217/handle/362003/2619]  |
| 专题 | 兰州化学物理研究所_固体润滑国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Wang XL. Synthesis and properties of novel poly(benzimidazopyrrolone amide)s containing pyridine moieties[J]. Journal of Applied Polymer Science,2008,109:3369-3375. |
| APA | 王晓龙.(2008).Synthesis and properties of novel poly(benzimidazopyrrolone amide)s containing pyridine moieties.Journal of Applied Polymer Science,109,3369-3375. |
| MLA | 王晓龙."Synthesis and properties of novel poly(benzimidazopyrrolone amide)s containing pyridine moieties".Journal of Applied Polymer Science 109(2008):3369-3375. |
入库方式： OAI收割
来源：兰州化学物理研究所
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