中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Densely stacked multilamellar and oligovesicular vesicles, bilayer cylinders, and tubes joining with vesicles of a salt-free catanionic extractant and surfactant system

文献类型:期刊论文

作者Yuan ZW(苑再武) ; Yin ZL(尹志雷) ; Sun SX(孙思修) ; Hao JC(郝京诚)
刊名Journal of Physical Chemistry B
出版日期2008
卷号112页码:1414-1419
ISSN号1520-6106
通讯作者郝京诚
中文摘要In the phase diagram of an excellent extractant of rare earth metal ions, di(2-ethylhexyl) phosphate (HDEHP, commercial name P204), mixing with a cationic trimethyltetradecylammonium hydroxide (TTAOH) in water, a birefringent L phase was found, which consists of densely stacked multilamellar vesicles. The densely stacked multilamellar vesicles are remarkably deformed, as observed by means of cryotransmission electron microscopy (cryo-TEM). Further, self-assembled structuressoligovesicular vesicles, bilayer cylinders, and tubes joining with vesiclesswere also observed. The self-assembled phase is transparent, anisotropic, and highly viscous, possessing elastic properties determined by rheological measurements. This is the first time that birefringent L phase with remarkably deformed amphiphilic bilayer membranes has been constructed through combining a hydrophobic organic extractant having double chains with a water-soluble surfactant having a single chain, which may direct primarily toward acquiring an understanding of the mechanism of salt-free catanionic vesicles and secondarily to determine if vesicle-extraction technology utilizing extractants is possible.
学科主题材料科学与物理化学
收录类别SCI
资助信息the NSFC (Grant 20625307)
语种英语
WOS记录号WOS:000252814700013
公开日期2013-03-28
源URL[http://210.77.64.217/handle/362003/2644]  
专题兰州化学物理研究所_固体润滑国家重点实验室
推荐引用方式
GB/T 7714
Yuan ZW,Yin ZL,Sun SX,et al. Densely stacked multilamellar and oligovesicular vesicles, bilayer cylinders, and tubes joining with vesicles of a salt-free catanionic extractant and surfactant system[J]. Journal of Physical Chemistry B,2008,112:1414-1419.
APA 苑再武,尹志雷,孙思修,&郝京诚.(2008).Densely stacked multilamellar and oligovesicular vesicles, bilayer cylinders, and tubes joining with vesicles of a salt-free catanionic extractant and surfactant system.Journal of Physical Chemistry B,112,1414-1419.
MLA 苑再武,et al."Densely stacked multilamellar and oligovesicular vesicles, bilayer cylinders, and tubes joining with vesicles of a salt-free catanionic extractant and surfactant system".Journal of Physical Chemistry B 112(2008):1414-1419.

入库方式: OAI收割

来源:兰州化学物理研究所

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