Functionalization of multiwalled carbon nanotube via surface reversible addition fragmentation chain transfer polymerization and as lubricant additives
文献类型：期刊论文
| 作者 | Liu WM(刘维民) ; Pei XW(裴小维)
|
| 刊名 | Journal of Polymer Science: Part A:Polymer Chemistry
 |
| 出版日期 | 2008 |
| 卷号 | 46页码:3014-3023 |
| 关键词 | carbon nanotubes functionalization of polymers lubricant additives reversible addition fragmentation chain transfer (RAFT) XPS |
| ISSN号 | 0887-624X |
| 通讯作者 | 郝京诚 |
| 中文摘要 | Polymer-grafted multiwalled carbon nanotube (MWCNT) hybrid composite which possess a hard backbone of MWCNT and a soft shell of brush-like polystyrene (PSt) were synthesized. The reversible addition fragmentation chain transfer (RAFT) agents were successfully immobilized onto the surface of MWCNT first, and PSt chains were subsequently grafted from sidewall of MWCNT via RAFT polymerization. Chemical structure of resulting product and the quantities of grafted polymer were determined by Fourier transform infrared, thermal gravimetric analysis, nuclear magnetic resonance, and X-ray photoelectron spectra. Transmission electron microscopy and field emission scanning electron microscopy images clearly indicate that the nanotubes were coated with a polymer layer. Furthermore, the functionalized MWCNT as additives was added to base lubricant and the tribological property of resultant MWCNT lubricant was investigated with four-ball machines. The results indicate that the functionalization led to an improvement in the dispersion of MWCNT and as additives it amended the tribological property of base lubricant. The mechanism of the significant improvements on the tribological properties of the functionalized MWCNT as additives was discussed. |
| 学科主题 | 材料科学与物理化学 |
| 收录类别 | SCI |
| 资助信息 | the NSFC (Grant NO. 50721062;20533080) |
| 语种 | 英语 |
| WOS记录号 | WOS:000255508500011 |
| 公开日期 | 2013-03-28 |
| 源URL | [http://210.77.64.217/handle/362003/2653]  |
| 专题 | 兰州化学物理研究所_固体润滑国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Liu WM,Pei XW. Functionalization of multiwalled carbon nanotube via surface reversible addition fragmentation chain transfer polymerization and as lubricant additives[J]. Journal of Polymer Science: Part A:Polymer Chemistry,2008,46:3014-3023. |
| APA | 刘维民,&裴小维.(2008).Functionalization of multiwalled carbon nanotube via surface reversible addition fragmentation chain transfer polymerization and as lubricant additives.Journal of Polymer Science: Part A:Polymer Chemistry,46,3014-3023. |
| MLA | 刘维民,et al."Functionalization of multiwalled carbon nanotube via surface reversible addition fragmentation chain transfer polymerization and as lubricant additives".Journal of Polymer Science: Part A:Polymer Chemistry 46(2008):3014-3023. |
入库方式： OAI收割
来源：兰州化学物理研究所
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