Nano/microtribological properties of ultrathin functionalized imidazolium wear-resistant ionic liquid films on single crystal silicon
文献类型:期刊论文
作者 | Mo YF(莫宇飞) ; Zhao WJ(赵文杰) ; Zhu M(朱敏) ; Bai MW(白明武) |
刊名 | Tribology Letters
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出版日期 | 2008 |
卷号 | 32页码:143-151 |
关键词 | Ionic liquid Lubricant Thin film Atomic force microscopy Friction Wear |
ISSN号 | 1023-8883 |
通讯作者 | 白明武 |
中文摘要 | Ionic liquids (ILs) are considered as a new kind of lubricant for micro/nanoelectromechanical system (M/NEMS) due to their excellent thermal and electrical conductivity. However, so far, only few reports have investigated the tribological behavior of molecular thin films of various ILs. Evaluating the nanoscale tribological performance of ILs when applied as a few nanometersthick film on a substrate is a critical step for their application in MEMS/NEMS devices. To this end, four kinds of ionic liquid carrying methyl, hydroxyl, nitrile, and carboxyl group were synthesized and these molecular thin films were prepared on single crystal silicon wafer by dipcoating method. Film thickness was determined by ellipsometric method. The chemical composition and morphology were characterized by the means of multitechnique X-ray photoelectron spectrometric analysis, and atomic force microscopic (AFM) analysis, respectively. The nano- and microtribological properties of the ionic liquid films were investigated. The morphologies of wear tracks of IL films were examined using a 3D non-contact interferometric microscope. The influence of temperature on friction and adhesion behavior at nanoscale, and the effect of sliding frequency and load on friction coefficient, load bearing capacity, and anti-wear durability at microscale were studied. Corresponding tribological mechanisms of IL films were investigated by AFM and ball-on-plane microtribotester. Friction reduction, adhesion resistance, and durability of IL films were dependent on their cation chemical structures, wettability, and ambient environment. |
学科主题 | 材料科学与物理化学 |
收录类别 | SCI |
资助信息 | National Natural Science Foundation of China (NSFC) under Grant Number 50675217;National 973 Program 2007CB607601 |
语种 | 英语 |
WOS记录号 | WOS:000261038000001 |
公开日期 | 2013-03-28 |
源URL | [http://210.77.64.217/handle/362003/2717] ![]() |
专题 | 兰州化学物理研究所_固体润滑国家重点实验室 |
推荐引用方式 GB/T 7714 | Mo YF,Zhao WJ,Zhu M,et al. Nano/microtribological properties of ultrathin functionalized imidazolium wear-resistant ionic liquid films on single crystal silicon[J]. Tribology Letters,2008,32:143-151. |
APA | 莫宇飞,赵文杰,朱敏,&白明武.(2008).Nano/microtribological properties of ultrathin functionalized imidazolium wear-resistant ionic liquid films on single crystal silicon.Tribology Letters,32,143-151. |
MLA | 莫宇飞,et al."Nano/microtribological properties of ultrathin functionalized imidazolium wear-resistant ionic liquid films on single crystal silicon".Tribology Letters 32(2008):143-151. |
入库方式: OAI收割
来源:兰州化学物理研究所
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