A novel metal-organic 1D-supramolecular complex from the self-assembly of copper(II) with 1,10-phenanthroline and biphthalate
文献类型：期刊论文
| 作者 | J. H. Bi ; F. H. Yao ; Z. X. Huang ; H. L. Wang ; N. L. Hu |
| 刊名 | Asian Journal of Chemistry
 |
| 出版日期 | 2007-12 |
| 卷号 | 19期号:7页码:5360-5364 |
| ISSN号 | 0970-7077 |
| 关键词 | Copper(II) 1 biphthalate 10-phenanthroline supramolecular crystal structure crystal-structure |
| 中文摘要 | A new copper(II) complex of formula [Cu(phen)(BPT)H2O]0.5H(2)O (phen = 1,10-phenanthroline, BPT = biphthalate) has been synthesized under the ambient conditions and the crystal structure was determined by single crystal X-ray diffraction. The compound crystallizes in the system and belongs to space group: orthorhombic Pca2(1) with a = 11.14770(10)angstrom, b = 11.63650(10)angstrom, c = 14.03150 (10)angstrom, 0 = 90 degrees, gamma = 90 degrees, V = 1820.17(3)angstrom(3), Z = 4, Dc = 1.587 g/cm(3), Mr = 434.88, mu(moKo) = 1.239 mm(-1), F(000) = 888. The final R = 0.0450 and wR = 0.1166 for 3012 observed reflections with I > sigma(I). The crystal structure analysis indicates that the copper(II) ion is five-coordinated in a square pyramidal geometry. The BPT and phen molecules are connected by copper(II) and form zigzag chain-like structure, then pack in 1D-supramolecular complex. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6111]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | J. H. Bi,F. H. Yao,Z. X. Huang,et al. A novel metal-organic 1D-supramolecular complex from the self-assembly of copper(II) with 1,10-phenanthroline and biphthalate[J]. Asian Journal of Chemistry,2007,19(7):5360-5364. |
| APA | J. H. Bi,F. H. Yao,Z. X. Huang,H. L. Wang,&N. L. Hu.(2007).A novel metal-organic 1D-supramolecular complex from the self-assembly of copper(II) with 1,10-phenanthroline and biphthalate.Asian Journal of Chemistry,19(7),5360-5364. |
| MLA | J. H. Bi,et al."A novel metal-organic 1D-supramolecular complex from the self-assembly of copper(II) with 1,10-phenanthroline and biphthalate".Asian Journal of Chemistry 19.7(2007):5360-5364. |
入库方式： OAI收割
来源：福建物质结构研究所
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