Silver iodobismuthates: Syntheses, structures, properties, and theoretical studies of Bi2Ag2I102- (n) and Bi4Ag2I162- (n)
文献类型:期刊论文
作者 | W. X. Chai ; L. M. Wu ; J. Q. Li ; L. Chen |
刊名 | Inorganic Chemistry
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出版日期 | 2007-02 |
卷号 | 46期号:4页码:1042-1044 |
关键词 | organic-inorganic perovskites crystal-structures bismuth iodide electronic-structure polymeric anions hybrid materials cation complex halides cs3bi2i9 |
ISSN号 | 0020-1669 |
中文摘要 | Two novel silver iodobismuthates have been obtained: (Et4N)(2n)-[Bi2Ag2I10](n) (1) with one-dimensional infinite chains built from bimetallic tetranuclear units and (Et4N)(2n)[Bi4Ag2I16](n) (2) with a two-dimensional 4(4) grid assembly of the tetranuclear Bi4I16 subunits as nodes and Ag atoms as linkages. Their optical band gaps, 2.05 and 1.93 eV, fit nicely in a size correlation of the Bi/I subunit, which is further supported by the density functional theory studies. |
语种 | 英语 |
公开日期 | 2013-04-01 |
源URL | [http://ir.fjirsm.ac.cn/handle/350002/6131] ![]() |
专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
推荐引用方式 GB/T 7714 | W. X. Chai,L. M. Wu,J. Q. Li,et al. Silver iodobismuthates: Syntheses, structures, properties, and theoretical studies of Bi2Ag2I102- (n) and Bi4Ag2I162- (n)[J]. Inorganic Chemistry,2007,46(4):1042-1044. |
APA | W. X. Chai,L. M. Wu,J. Q. Li,&L. Chen.(2007).Silver iodobismuthates: Syntheses, structures, properties, and theoretical studies of Bi2Ag2I102- (n) and Bi4Ag2I162- (n).Inorganic Chemistry,46(4),1042-1044. |
MLA | W. X. Chai,et al."Silver iodobismuthates: Syntheses, structures, properties, and theoretical studies of Bi2Ag2I102- (n) and Bi4Ag2I162- (n)".Inorganic Chemistry 46.4(2007):1042-1044. |
入库方式: OAI收割
来源:福建物质结构研究所
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