Partition, luminescence and energy transfer of Er3+/Yb3+ ions in oxyfluoride glass ceramic containing CaF2 nano-crystals
文献类型:期刊论文
作者 | D. Q. Chen ; Y. S. Wang ; E. Ma ; Y. L. Yu ; F. Liu |
刊名 | Optical Materials
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出版日期 | 2007-08 |
卷号 | 29期号:12页码:1693-1699 |
关键词 | oxyfluoride glass ceramics CaF2 nano-crystals energy transfer luminescence up-conversion up-conversion spectroscopic properties er3+ ions laser yb3+ nanocrystals behavior |
ISSN号 | 0925-3467 |
中文摘要 | A complete spectroscopic investigation of energy transfer processes in oxyfluoride glass ceramics containing CaF2 nano-crystals doped with various amounts of Er3+ and Yb3+ was reported. An enhancement of the 1.53 mu m emission and infrared to visible up-conversion fluorescence was confirmed experimentally due to efficient non-radiative energy transfer from Yb3+ to Er3+ ions concentrated in CaF2 nano-crystals. The efficiency of Yb3+ to Er3+ energy transfer in excess of 85% was obtained for 0.5 mol% Er3+/2.0 mol% Yb3+ co-doped glass ceramic. Using rate equation formulism, the coefficient of Yb3+ to Er 3+ energy transfer was determined to be about 3.5 times higher than that of Er3+ to Yb3+ energy back transfer, which is sufficient to provide high I-4(11/2) population of Er3+ to improve the fluorescence of the co-doped glass ceramics. (c) 2006 Elsevier B.V. All rights reserved. |
语种 | 英语 |
公开日期 | 2013-04-01 |
源URL | [http://ir.fjirsm.ac.cn/handle/350002/6135] ![]() |
专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
推荐引用方式 GB/T 7714 | D. Q. Chen,Y. S. Wang,E. Ma,et al. Partition, luminescence and energy transfer of Er3+/Yb3+ ions in oxyfluoride glass ceramic containing CaF2 nano-crystals[J]. Optical Materials,2007,29(12):1693-1699. |
APA | D. Q. Chen,Y. S. Wang,E. Ma,Y. L. Yu,&F. Liu.(2007).Partition, luminescence and energy transfer of Er3+/Yb3+ ions in oxyfluoride glass ceramic containing CaF2 nano-crystals.Optical Materials,29(12),1693-1699. |
MLA | D. Q. Chen,et al."Partition, luminescence and energy transfer of Er3+/Yb3+ ions in oxyfluoride glass ceramic containing CaF2 nano-crystals".Optical Materials 29.12(2007):1693-1699. |
入库方式: OAI收割
来源:福建物质结构研究所
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