Synthesis and structural characterization of a cyano-bridged 1-D Lanthanum(III)-iron(III) complex La(DMSO)(5)(H2O) (mu-CN)(2) Fe(CN)(4) center dot H2O
文献类型：期刊论文
| 作者 | W. T. Chen ; G. C. Guo ; L. Z. Cai ; H. F. Chen ; G. Xu ; J. S. Huang |
| 刊名 | Chinese Journal of Structural Chemistry
 |
| 出版日期 | 2007 |
| 卷号 | 26期号:10页码:1239-1242 |
| 关键词 | crystal structure cyano-bridged lanthanum complex Prussian blue 4f-3d coordination polymers crystal-structure magnetic-properties bimetallic complex |
| ISSN号 | 0254-5861 |
| 中文摘要 | A new lanthanum(III)-iron(III), complex [La(DMSO)(5)(H2O)](mu-CN)(2)[Fe(CN)(4)]center dot H2O 1(DMSO = dimethylsulfoxide) has been prepared by a facile approach, ball-milling method, and characterized by X-ray diffraction. The crystal belongs to monoclinic, space group P2(1)In with a = 9.7125(3), b = 21.5336(7), c = 14.3804(5) angstrom, beta = 93.242(3), C16H34FeLaN6O7S5, M-r = 777.55, V = 3002.8(2) angstrom(3), Z = 4, D-c = 1.720 g/cm(3), S = 1.053, p(mu MoK alpha) = 2.278 mm (-1), F(000) = 1564, R = 0.0490 and wR = 0.1270. The crystal structure analysis of 1 reveals a slightly distorted square-antiprism eightfold-coordinated U(III) ion and a 1-D zigzag chain structure extending through the Fe-CN-La-NC-Fe linkages. The [La(DMSO)(5)(H2O)](mu-CN)(2)[Fe(CN)(4)] species are held together via hydrogen bonds to form a three-dimensional framework. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6164]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | W. T. Chen,G. C. Guo,L. Z. Cai,et al. Synthesis and structural characterization of a cyano-bridged 1-D Lanthanum(III)-iron(III) complex La(DMSO)(5)(H2O) (mu-CN)(2) Fe(CN)(4) center dot H2O[J]. Chinese Journal of Structural Chemistry,2007,26(10):1239-1242. |
| APA | W. T. Chen,G. C. Guo,L. Z. Cai,H. F. Chen,G. Xu,&J. S. Huang.(2007).Synthesis and structural characterization of a cyano-bridged 1-D Lanthanum(III)-iron(III) complex La(DMSO)(5)(H2O) (mu-CN)(2) Fe(CN)(4) center dot H2O.Chinese Journal of Structural Chemistry,26(10),1239-1242. |
| MLA | W. T. Chen,et al."Synthesis and structural characterization of a cyano-bridged 1-D Lanthanum(III)-iron(III) complex La(DMSO)(5)(H2O) (mu-CN)(2) Fe(CN)(4) center dot H2O".Chinese Journal of Structural Chemistry 26.10(2007):1239-1242. |
入库方式： OAI收割
来源：福建物质结构研究所
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