Self-assembly and characterization of cyano-bridged bimetallic Ln-Fe and Ln-Co complexes (Ln = La, Pr, Nd and Sm). Nature of the magnetic interactions between the Ln(3+) and Fe3+ ions
文献类型：期刊论文
| 作者 | W. T. Chen ; G. C. Guo ; M. S. Wang ; G. Xu ; L. Z. Cai ; T. Akitsu ; M. Akita-Tanaka ; A. Matsushita ; J. S. Huang |
| 刊名 | Inorganic Chemistry
 |
| 出版日期 | 2007-03 |
| 卷号 | 46期号:6页码:2105-2114 |
| 关键词 | heptanuclear heterobimetallic complexes hexacyanometalate molecular chemistry one-dimensional chain ladder-type compounds crystal-structure structural-characterization building-blocks photoinduced magnetization 2-dimensional ferrimagnet coordination polymers |
| ISSN号 | 0020-1669 |
| 中文摘要 | Two structural series, including seven isomorphous heterodinuclear complexes, [Ln(DMSO)(4)(H2O)(3)(mu-CN)M(CN)(5)]center dot H2O ([La-Fe] (1), [Pr-Fe] (2), [Pr-Co] (3), [Nd-Fe] (4), [Nd-Co] (5), [Sm-Fe] (6) and [Sm-Co] (7)), and seven isostructural 2-D stairlike cyano-bridged bimetallic assemblies, [Ln(DMSO)(2)(H2O)(mu-CN)(4)M(CN)(2)](n) ([La-Fe](n) (8), [Pr-Fe](n) (9), [Pr-Co](n) (10), [Nd-Fe](n) (11), [Nd-Co](n) (12), [Sm-Fe](n) (13) and [Sm-Co](n) (14)) (DMSO = dimethylsulfoxide), have been rationally prepared by a facile approach, a ball-milling method, and characterized by X-ray diffraction and magnetic measurements. The isomorphous structures, in conjunction with the diamagnetism of the Co3+ and La3+ ions, allow an approximation to the nature of coupling between the iron(III) and lanthanide(III) ions in the Ln(3+)-Fe3+ complexes. The Ln(3+)-Fe3+ interaction is ferromagnetic for the dinuclear [Pr-Fe] (2), [Nd-Fe] (4), and [Sm-Fe] (6) systems and for the 2-D [Pr-Fe](n) (9), [Nd-Fe](n) (11), and [Sm-Fe](n) (13) assemblies. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6167]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | W. T. Chen,G. C. Guo,M. S. Wang,et al. Self-assembly and characterization of cyano-bridged bimetallic Ln-Fe and Ln-Co complexes (Ln = La, Pr, Nd and Sm). Nature of the magnetic interactions between the Ln(3+) and Fe3+ ions[J]. Inorganic Chemistry,2007,46(6):2105-2114. |
| APA | W. T. Chen.,G. C. Guo.,M. S. Wang.,G. Xu.,L. Z. Cai.,...&J. S. Huang.(2007).Self-assembly and characterization of cyano-bridged bimetallic Ln-Fe and Ln-Co complexes (Ln = La, Pr, Nd and Sm). Nature of the magnetic interactions between the Ln(3+) and Fe3+ ions.Inorganic Chemistry,46(6),2105-2114. |
| MLA | W. T. Chen,et al."Self-assembly and characterization of cyano-bridged bimetallic Ln-Fe and Ln-Co complexes (Ln = La, Pr, Nd and Sm). Nature of the magnetic interactions between the Ln(3+) and Fe3+ ions".Inorganic Chemistry 46.6(2007):2105-2114. |
入库方式： OAI收割
来源：福建物质结构研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。