Synthesis and characterization of luminescent Pt-II-Cu-I heteronuclear complex Pt4Cu2(edt)(4)(PPh3)(6) (ClO4)(2)(4H(2)O) (edt=1,2-ethanedithiolate)
文献类型：期刊论文
| 作者 | Y. D. Chen ; L. X. Shi ; Y. M. Zhu ; L. Y. Zhang ; Z. N. Chen |
| 刊名 | Chinese Journal of Inorganic Chemistry
 |
| 出版日期 | 2007-07 |
| 卷号 | 23期号:7页码:1303-1305 |
| 关键词 | 1 2-ethanedithiol coppe(I) heteronuclear luminescent platinum(II) pt(diimine)(dithiolate) state |
| ISSN号 | 1001-4861 |
| 中文摘要 | Self-assembly between Pt(phen)(edt) (phen=phenanthroline, edt=1,2-ethanedithiolate) and [Cu(PPh3)(2) (MeCN)(2)](ClO4) (PPh3=triphenylphosphine) gave rise to formation of heterohexanuclear complex [Pt4Cu2(edt)(4)(PPh3)(6)](ClO4)(2) (4H(2)O) (1). The complex was characterized by elemental analyses, ES-MS, UV-Vis, IR, P-31 NMR spectroscopy and X-ray crystallography. The molecule consists of two [PtCu(edt)(2)(PPh3)(3)] units which has a centrosymmmetric inversion to give a cyclic heterohexanuclear skeleton. The Pt (II) and Cu (1) center adopt square-planar and trigonal coordination modes, respectively. The compound shows intense emission at 632 nm in the solid state and at 678 mn in frozen dichloromethane glass at 77 K. |
| 语种 | 中文 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6183]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | Y. D. Chen,L. X. Shi,Y. M. Zhu,et al. Synthesis and characterization of luminescent Pt-II-Cu-I heteronuclear complex Pt4Cu2(edt)(4)(PPh3)(6) (ClO4)(2)(4H(2)O) (edt=1,2-ethanedithiolate)[J]. Chinese Journal of Inorganic Chemistry,2007,23(7):1303-1305. |
| APA | Y. D. Chen,L. X. Shi,Y. M. Zhu,L. Y. Zhang,&Z. N. Chen.(2007).Synthesis and characterization of luminescent Pt-II-Cu-I heteronuclear complex Pt4Cu2(edt)(4)(PPh3)(6) (ClO4)(2)(4H(2)O) (edt=1,2-ethanedithiolate).Chinese Journal of Inorganic Chemistry,23(7),1303-1305. |
| MLA | Y. D. Chen,et al."Synthesis and characterization of luminescent Pt-II-Cu-I heteronuclear complex Pt4Cu2(edt)(4)(PPh3)(6) (ClO4)(2)(4H(2)O) (edt=1,2-ethanedithiolate)".Chinese Journal of Inorganic Chemistry 23.7(2007):1303-1305. |
入库方式： OAI收割
来源：福建物质结构研究所
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