A series of lanthanide-transition metal frameworks based on 1-, 2-, and 3D metal-organic motifs linked by different 1D copper(I) halide motifs
文献类型：期刊论文
| 作者 | J. W. Cheng ; S. T. Zheng ; G. Y. Yang |
| 刊名 | Inorganic Chemistry
 |
| 出版日期 | 2007-11 |
| 卷号 | 46期号:24页码:10261-10267 |
| 关键词 | coordination polymers oxide chains heteronuclear complexes crystal-structure clusters networks architectures magnetism linkages design |
| ISSN号 | 0020-1669 |
| 中文摘要 | Hydrothermal reactions of lanthanide(ill) oxide and copper halide with isonicotinic acid (Hina) and pyridine-2,3-dicarboxylic acid (H(2)pdc) or 1,2-benzenedicarboxylic acid (H(2)bdc) lead to three novel lanthanide(III)-copper(I) heterometallic compounds, namely, [Ce-2(ina)(5)(na)(2)(H2O)(2)][Cu5Br4] (1, na = nicotinic acid), [Er-4(ina)(8)(bdc)(2)(OH)(H2O)(5)][CU(8)l(7)] (2), and [Ce-3(ina)(8)(bdc)(H2O)(4)][CU7Br6] (3). Compound 1 is constructed from two distinct units of the Ln-organic double chains and inorganic [CU5Br4](n)(n+) chains. Compound 2 consists of 2D Ln-organic layers and 1D [CU(8)l(7)](n)(n+) cluster chains. Compound 3 can be viewed as a 1D [CU6Br6](n) chainlike motif inserted into the channels of a 3D Ln-Cu-organic motif. Compounds 1-3 exhibit three different 1D inorganic copper(I)-halide chains interconnected with metal-organic 1D chains, 2D layers, and 3D nets resulting in three mixed-motif non-interpenetrating heterometallic Cu-halide-lanthanide (Ln)-organic frameworks, which represent good examples and a facile method to construct such mixed-motif heterometallic compounds. Furthermore, the IR, TGA, and UV-vis spectra of 1-3 were also studied. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6198]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | J. W. Cheng,S. T. Zheng,G. Y. Yang. A series of lanthanide-transition metal frameworks based on 1-, 2-, and 3D metal-organic motifs linked by different 1D copper(I) halide motifs[J]. Inorganic Chemistry,2007,46(24):10261-10267. |
| APA | J. W. Cheng,S. T. Zheng,&G. Y. Yang.(2007).A series of lanthanide-transition metal frameworks based on 1-, 2-, and 3D metal-organic motifs linked by different 1D copper(I) halide motifs.Inorganic Chemistry,46(24),10261-10267. |
| MLA | J. W. Cheng,et al."A series of lanthanide-transition metal frameworks based on 1-, 2-, and 3D metal-organic motifs linked by different 1D copper(I) halide motifs".Inorganic Chemistry 46.24(2007):10261-10267. |
入库方式： OAI收割
来源：福建物质结构研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。