Synthesis and crystal structure of a model for the active sites of Fe-only hydrogenases: Fe-2(SCH2)(2)N(3-PhCF3)CO)(6) (2)
文献类型：期刊论文
| 作者 | L. X. Cheng ; C. B. Ma ; M. Q. Hu ; C. N. Chen ; Q. T. Liu |
| 刊名 | Chinese Journal of Structural Chemistry
 |
| 出版日期 | 2007 |
| 卷号 | 26期号:1页码:113-117 |
| 关键词 | Fe-only hydrogenases crystal structure iron-sulfur cluster reduction |
| ISSN号 | 0254-5861 |
| 中文摘要 | A model compound for the active sites of Fe-only hydrogenases, [Fe-2(SCH2)(2)N(3-PhCF3)(CO)(6)](2), has been synthesized and structurally characterized by single-crystal X-ray diffraction. It crystallizes in tetragonal, space group P4(3), with a 12.6324(3), b = 12.6324(3), c = 24.0453(12) angstrom, V = 3837.1(2) angstrom(3), Z = 4, Fe4S4N2C30O12F6H16, M-r = 1062.09, D-c = 1.839 g/cm(3), mu(MoK alpha) = 1.791 mm(-1), F(000) = 2112, T = 293(2) K, Flack = 0.034(9), R = 0.0282 and wR = 0.0685 for 8148 observed reflections with I > 2 sigma(I). In the title compound, each Fel atom is coordinated by three terminal carbonyl C atoms (Fe-C: 1.783(3)similar to 1.816(3) angstrom), two bridging S atoms (Fe-S: 2.2609(7)similar to 2.2757(8) angstrom) and another Fe atom (Fe-Fe 2.5011(5) angstrom), adopting a distorted octahedral geometry with trans angles ranging from 152.45(11) to 157.77(10)degrees. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6205]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | L. X. Cheng,C. B. Ma,M. Q. Hu,et al. Synthesis and crystal structure of a model for the active sites of Fe-only hydrogenases: Fe-2(SCH2)(2)N(3-PhCF3)CO)(6) (2)[J]. Chinese Journal of Structural Chemistry,2007,26(1):113-117. |
| APA | L. X. Cheng,C. B. Ma,M. Q. Hu,C. N. Chen,&Q. T. Liu.(2007).Synthesis and crystal structure of a model for the active sites of Fe-only hydrogenases: Fe-2(SCH2)(2)N(3-PhCF3)CO)(6) (2).Chinese Journal of Structural Chemistry,26(1),113-117. |
| MLA | L. X. Cheng,et al."Synthesis and crystal structure of a model for the active sites of Fe-only hydrogenases: Fe-2(SCH2)(2)N(3-PhCF3)CO)(6) (2)".Chinese Journal of Structural Chemistry 26.1(2007):113-117. |
入库方式： OAI收割
来源：福建物质结构研究所
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