Synthesis and crystal structure of K(18-crown-6) (3)P-11 center dot 2en
文献类型：期刊论文
| 作者 | F. R. Dai ; L. Xu |
| 刊名 | Chinese Journal of Structural Chemistry
 |
| 出版日期 | 2007 |
| 卷号 | 26期号:1页码:45-48 |
| 关键词 | zintl ions phosphorus crystal structure undecaphosphide primary phosphane polyphosphides phosphides chemistry anions rb4p6 |
| ISSN号 | 0254-5861 |
| 中文摘要 | The undecaphosphide anion in ethylenediamine/18-crown-6 solution is isolated as [K(18-crown-6)](3)P-11 center dot 2en 1. The crystal structure has been determined by single-crystal X-ray diffraction. The crystal is of monoclinic, space group P2(1) with a = 13.4731(7), b = 16.1123(6), c = 16.5117(g) angstrom, beta = 112.133(2)degrees, V = 3320.3(3) angstrom(3), D-c = 1.371 g/cm(3) C40H88K3N4O18P11, M-r = 1371.11, F(000) 1444, mu = 0.532 mm(-1), Z = 2, R = 0.0544 and wR = 0.1326 for 11423 observed reflections (I > 2 sigma(I)). The "naked" P-11(3-) ion is stabilized by two partly sequestered potassiums. The third partly sequestered potassium does not interact with the P atom (P(6)) but with two solvent molecules. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6209]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | F. R. Dai,L. Xu. Synthesis and crystal structure of K(18-crown-6) (3)P-11 center dot 2en[J]. Chinese Journal of Structural Chemistry,2007,26(1):45-48. |
| APA | F. R. Dai,&L. Xu.(2007).Synthesis and crystal structure of K(18-crown-6) (3)P-11 center dot 2en.Chinese Journal of Structural Chemistry,26(1),45-48. |
| MLA | F. R. Dai,et al."Synthesis and crystal structure of K(18-crown-6) (3)P-11 center dot 2en".Chinese Journal of Structural Chemistry 26.1(2007):45-48. |
入库方式： OAI收割
来源：福建物质结构研究所
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