Novel cadmium(II) phosphonatophenylsulfonate cluster compounds: Syntheses, structures, and luminescent properties
文献类型：期刊论文
| 作者 | Z. Y. Du ; X. L. Li ; Q. Y. Liu ; J. G. Mao |
| 刊名 | Crystal Growth & Design
 |
| 出版日期 | 2007-08 |
| 卷号 | 7期号:8页码:1501-1507 |
| 关键词 | crystal-structures metal phosphonates pyrazole ligands hybrid compounds tetranuclear frameworks design cage 1d pyridylphosphonates |
| ISSN号 | 1528-7483 |
| 中文摘要 | Hydrothermal reactions of cadmium(II) salt with m-phosphonophenylsulfonic acid (H3L) and 1,10-phenanthroline (phen) or 4,4'-bipyridine (bipy) led to three novel cadmium(II) phosphonatephenylsulfonates, namely, [Cd-4(L)(2)(phen)(6)(Cl)(2)(H2O)(2)]center dot 14H(2)O (1), [Cd-6(L)(4)(phen)(8)]center dot 14H(2)O (2), and [Cd-3(L)(2)(bipy)(3)(H2O)(6)]center dot 4H(2)O (3). Compound 1 contains a tetranuclear cadmium(II) cluster in which four cadmium(II) ions are bridged by two tetradentate phosphonate groups. Compound 2 features a hexanuclear cadmium(II) cage in which six cadmium(II) ions are bridged by one tetradentate and three pentadentate phosphonate groups. The structure of compound 3 features a novel 3D network based on 1D chains of [Cd-3(L)(2)] cross-linked by 4,4'-bipy ligands; its topological structure is similar to that of CdSO4. Compounds 1-3 exhibit broad blue fluorescence emission bands at 408, 410, and 396 nm, respectively. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6217]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | Z. Y. Du,X. L. Li,Q. Y. Liu,et al. Novel cadmium(II) phosphonatophenylsulfonate cluster compounds: Syntheses, structures, and luminescent properties[J]. Crystal Growth & Design,2007,7(8):1501-1507. |
| APA | Z. Y. Du,X. L. Li,Q. Y. Liu,&J. G. Mao.(2007).Novel cadmium(II) phosphonatophenylsulfonate cluster compounds: Syntheses, structures, and luminescent properties.Crystal Growth & Design,7(8),1501-1507. |
| MLA | Z. Y. Du,et al."Novel cadmium(II) phosphonatophenylsulfonate cluster compounds: Syntheses, structures, and luminescent properties".Crystal Growth & Design 7.8(2007):1501-1507. |
入库方式： OAI收割
来源：福建物质结构研究所
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