Novel Manganese(II) sulfonate-phosphonates with dinuclear, tetranuclear, and hexanuclear clusters
文献类型：期刊论文
| 作者 | Z. Y. Du ; A. V. Prosvirin ; J. G. Mao |
| 刊名 | Inorganic Chemistry
 |
| 出版日期 | 2007-11 |
| 卷号 | 46期号:23页码:9884-9894 |
| 关键词 | magnetic-properties crystal-structures pyrazole ligands metal diphosphonates cage complexes mn acid phosphonocarboxylates nickel(ii) cobalt(ii) |
| ISSN号 | 0020-1669 |
| 中文摘要 | Hydrothermal reactions of manganese(II) salts with m-sulfophenylphosphonic acid (m-HO3S-Ph-PO3H2, H3L) and 1,10-phenanthroline (phen) led to six novel manganese(II) sulfonate-phosphonates, namely, [Mn-2(HL)(2)(phen)(4)][Mn-2(HL)(2)(phen)(4)(H2O)](2)center dot 6H(2)O (1), [Mn-4(L)(2)(phen)(8)(H2O)(2)][ClO4](2)center dot 3H(2)O (2), [Mn(phen)(H2O)(4)](2)[Mn-4(L)(4)(phen)(4)]center dot 10H(2)O (3), [Mn-6(L)(4)(phen)(8)(H2O)(2)]center dot 4H(2)O (4), [Mn-6(L)(4)(phen)(8)(H2O)(2)]center dot 24H(2)O (5), and [Mn-6(L)(4)(Phen)(6)(H2O)(4)]center dot 5H(2)O (6). The structure of 1 contains two types of dinuclear manganese(II) clusters, and 2-3 exhibit two types of tetranuclear manganese(II) cluster units. 4-5 feature two different types of isolated hexanuclear manganese(II) clusters, whereas the hexanuclear manganese(II) clusters in 6 are bridged by sulfonate-phosphonate ligands into a 1D chain. Magnetic property measurements indicate that there exist weak antiferromagnetic interactions between magnetic centers in all six compounds. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6219]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | Z. Y. Du,A. V. Prosvirin,J. G. Mao. Novel Manganese(II) sulfonate-phosphonates with dinuclear, tetranuclear, and hexanuclear clusters[J]. Inorganic Chemistry,2007,46(23):9884-9894. |
| APA | Z. Y. Du,A. V. Prosvirin,&J. G. Mao.(2007).Novel Manganese(II) sulfonate-phosphonates with dinuclear, tetranuclear, and hexanuclear clusters.Inorganic Chemistry,46(23),9884-9894. |
| MLA | Z. Y. Du,et al."Novel Manganese(II) sulfonate-phosphonates with dinuclear, tetranuclear, and hexanuclear clusters".Inorganic Chemistry 46.23(2007):9884-9894. |
入库方式： OAI收割
来源：福建物质结构研究所
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