Syntheses, crystal structures and photoluminescences of two (4,4) topological coordination networks derived from the flexible bipyridyl ligands
文献类型：期刊论文
| 作者 | Y. Q. Gong ; J. T. Chen ; D. Q. Yuan ; M. Y. Wu ; Y. G. Huang ; F. L. Jiang ; M. C. Hong |
| 刊名 | Inorganica Chimica Acta
 |
| 出版日期 | 2007-05 |
| 卷号 | 360期号:7页码:2207-2214 |
| 关键词 | silver coordination polymer crystal structure photoluminescent properties bidentate binaphthol derivatives metal-organic frameworks porous solids silver(i) complexes rational design polymers 3d dinuclear chemistry anions |
| ISSN号 | 0020-1693 |
| 中文摘要 | Two new 2D coordination polymers, [Ag-4(mu-4,4'-bPP)(3)(1,3-bdc)(2)](n) center dot 2nH(2)O (1) and [Ag(mu-4,4'-bPP)(2)ClO4](n) (2) (4,4'-bpp = 2,2'-bis(4-pyridylmethyleneoxy)-1,1'-biphenylene; 1,3-bdc = 1,3-benzenedicarboxylate) have been synthesized using three-layer diffusion methods. Single-crystal X-ray analyses reveal that they are both extended grid networks of the (4,4) topology. In complex 1, a chain built by Ag(I) centers with T-shaped and linear geometries is further connected by the interesting ligand-unsupported Ag center dot center dot center dot Ag interactions as well as the conjugated Tu systems to form an interdigitated 2-D coordination network. The corrugated (4,4) sheets of 2 are packed in the ab planes and stacked along the c direction with the anions ClO4- occupying the gaps in the squares. (C) 2006 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6269]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | Y. Q. Gong,J. T. Chen,D. Q. Yuan,et al. Syntheses, crystal structures and photoluminescences of two (4,4) topological coordination networks derived from the flexible bipyridyl ligands[J]. Inorganica Chimica Acta,2007,360(7):2207-2214. |
| APA | Y. Q. Gong.,J. T. Chen.,D. Q. Yuan.,M. Y. Wu.,Y. G. Huang.,...&M. C. Hong.(2007).Syntheses, crystal structures and photoluminescences of two (4,4) topological coordination networks derived from the flexible bipyridyl ligands.Inorganica Chimica Acta,360(7),2207-2214. |
| MLA | Y. Q. Gong,et al."Syntheses, crystal structures and photoluminescences of two (4,4) topological coordination networks derived from the flexible bipyridyl ligands".Inorganica Chimica Acta 360.7(2007):2207-2214. |
入库方式： OAI收割
来源：福建物质结构研究所
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