Chains, ladders and sheets of d(10) metal-organic polymers generated from the flexible bipyridyl ligands
文献类型：期刊论文
| 作者 | Y. Q. Gong ; R. H. Wang ; D. Q. Yuan ; W. P. Su ; Y. G. Huang ; C. Y. Yue ; F. L. Jiang ; M. C. Hong |
| 刊名 | Polyhedron
 |
| 出版日期 | 2007-11 |
| 卷号 | 26期号:18页码:5309-5316 |
| 关键词 | flexible bipyridyl d(10) metal multi-carboxylate crystal structure coordination polymer optical properties coordination polymers crystal-structures hydrothermal synthesis mixed-ligands silver(i) networks solids frameworks complexes copper(i) |
| ISSN号 | 0277-5387 |
| 中文摘要 | By use of the three-layer diffusion method, reactions of flexible bipyridyl ligands (4,4'-bpp or 3,3'-bpp) with M(II) salts (M = Zn, Cd) and multi-carboxylate ligands resulted in the formation of four interesting d(10) metal-organic coordination polymers: [Zn(mu-4,4'-bpp)Br-2](n) (1), [Zn(mu-4,4'-bpp)(l,2-bdc)](n) center dot nH(2)O (2), [Zn(mu-3,3'-bpp)(1,3-bdc)](n) center dot nCH(3)OH center dot 2nH(2)O (3) and [Cd(mu-3,3'-bpp)(C4H2O4)](n) center dot 3nH(2)O (4) (4,4'-bpp = 2,2'-bis(4-pyridylmethyleneoxy)- 1,1'-biphenylene; 3,3'-bpp = 2,2 '-bis(3-pyridylmethyleneoxy)-1,1'-biphenylene; bdc=benzenedicarboxylate, C4H4O4 = fumaric acid). Complex 1 has a 2D sheet structure consisting of two unusual zigzag Zn(II) chains which are nearly perpendicular to each other. Complex 2 is comprised of two-leg ladders, in which [Zn(4,4'-bpp)] chains serve as the side rails and 1,2-bdc ligands serve as the cross rungs. In complex 3, every two 1,3-bdc ligands connect the neighbouring Zn(II)-3,3'-bpp dimetallic rings in eta(1) coordination modes into an interesting chain structure. Complex 4 consists of an anionic macrocycle-containing cadmium dicarboxylate sheets that are separated by 3,3'-bpp. These d(10) metal complexes exhibit high thermal stabilities and strong luminescence efficiencies. (c) 2007 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6271]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | Y. Q. Gong,R. H. Wang,D. Q. Yuan,et al. Chains, ladders and sheets of d(10) metal-organic polymers generated from the flexible bipyridyl ligands[J]. Polyhedron,2007,26(18):5309-5316. |
| APA | Y. Q. Gong.,R. H. Wang.,D. Q. Yuan.,W. P. Su.,Y. G. Huang.,...&M. C. Hong.(2007).Chains, ladders and sheets of d(10) metal-organic polymers generated from the flexible bipyridyl ligands.Polyhedron,26(18),5309-5316. |
| MLA | Y. Q. Gong,et al."Chains, ladders and sheets of d(10) metal-organic polymers generated from the flexible bipyridyl ligands".Polyhedron 26.18(2007):5309-5316. |
入库方式： OAI收割
来源：福建物质结构研究所
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