A series of cadmium(II) coordination polymers synthesized at different pH values
文献类型：期刊论文
| 作者 | Z. G. Guo ; R. Cao ; X. J. Li ; D. Q. Yuan ; W. H. Bi ; X. D. Zhu ; Y. F. Li |
| 刊名 | European Journal of Inorganic Chemistry
 |
| 出版日期 | 2007-02 |
| 期号 | 5页码:742-748 |
| ISSN号 | 1434-1948 |
| 关键词 | cadmium polymers self-assembly photoluminescence metal-organic framework crystal-structures hydrothermal syntheses emission properties magnetic-properties selective binding trimesic acid ligands 3-(2-pyridyl)pyrazole terephthalate |
| 中文摘要 | A new family of cadmium(II) coordination polymers, {[Cd(Hbic)(2)center dot(H2O)(2)]center dot 2H(2)O}(n) (1), [Cd(Hbic)(2)](n) (2), [Cd(Hbic)(2)center dot (H2O)](n) (3), H(2)bic = 1H-benzimidazole-5-carboxylic acid, has been hydrothermally prepared by the assembly of Cd` with H(2)bic. A change in the pH values resulted in a series of compounds with different compositions and dimensionalities. Formed at the lowest pH, compound 1 has a two-dimensional supramolecular structure, which contains 1D chains ex- tended by hydrogen bonds. At a slightly higher pH, compound 2 is synthesized with a higher number of deprotonated carboxylate groups per cadmium atom. A further increase in the pH leads to 3D dinuclear compound 3 with yellow-green emitting fluorescence. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007). |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6279]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | Z. G. Guo,R. Cao,X. J. Li,et al. A series of cadmium(II) coordination polymers synthesized at different pH values[J]. European Journal of Inorganic Chemistry,2007(5):742-748. |
| APA | Z. G. Guo.,R. Cao.,X. J. Li.,D. Q. Yuan.,W. H. Bi.,...&Y. F. Li.(2007).A series of cadmium(II) coordination polymers synthesized at different pH values.European Journal of Inorganic Chemistry(5),742-748. |
| MLA | Z. G. Guo,et al."A series of cadmium(II) coordination polymers synthesized at different pH values".European Journal of Inorganic Chemistry .5(2007):742-748. |
入库方式： OAI收割
来源：福建物质结构研究所
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