Diiron models for the active site of Fe-only hydrogenase with terminal organosulfur ligation: Synthesis, structures and electrochemistry
文献类型：期刊论文
| 作者 | M. Q. Hu ; C. B. Ma ; Y. T. Si ; C. N. Chen ; Q. T. Liu |
| 刊名 | Journal of Inorganic Biochemistry
 |
| 出版日期 | 2007-10 |
| 卷号 | 101期号:10页码:1370-1375 |
| 关键词 | bioinorganic chemistry Fe-only hydrogenase iron complex organometallic complexes organosulfur ligand iron hydrogenase desulfovibrio-desulfuricans proton reduction carbene ligands complexes coordination exchange catalysis evolution property |
| ISSN号 | 0162-0134 |
| 中文摘要 | Diiron model complexes (mu-SCH(2)CH(2)CH(2)S)Fe(2)(CO)(5)L with thioether-substitution, L = S(CH(2)CH(3))(2) (2), S(CH(2)CH(3))(CH(2)CH(2)Cl) (3), S(CH(2)CH(3))(C(6)H(5)) (4), or sulfoxide-substitution, L = SO(CH(2)CH(2)CH(3))(2) (5), SO(CH(3))(2) (6), were synthesized as active site analogues of Fe-only hydrogenase. The organosulfur ligands were introduced into the diiron centers via moderately stable intermediates following two routes. The X-ray crystallographic structures of complexes 2-6 show the apical positions of terminal organosulfur ligands. The electrochemical behaviors of the model complexes were investigated, especially for the interesting properties of the derivative of 6 which is proposed to be the first model with weak donor ligand similar to CO. (C) 2007 Elsevier Inc. All rights reserved. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6293]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | M. Q. Hu,C. B. Ma,Y. T. Si,et al. Diiron models for the active site of Fe-only hydrogenase with terminal organosulfur ligation: Synthesis, structures and electrochemistry[J]. Journal of Inorganic Biochemistry,2007,101(10):1370-1375. |
| APA | M. Q. Hu,C. B. Ma,Y. T. Si,C. N. Chen,&Q. T. Liu.(2007).Diiron models for the active site of Fe-only hydrogenase with terminal organosulfur ligation: Synthesis, structures and electrochemistry.Journal of Inorganic Biochemistry,101(10),1370-1375. |
| MLA | M. Q. Hu,et al."Diiron models for the active site of Fe-only hydrogenase with terminal organosulfur ligation: Synthesis, structures and electrochemistry".Journal of Inorganic Biochemistry 101.10(2007):1370-1375. |
入库方式： OAI收割
来源：福建物质结构研究所
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