Synthesis and structure of a dinuclear copper(II)-ditetrazolate involving in situ ligand synthesis
文献类型：期刊论文
| 作者 | X. H. Huang ; T. L. Sheng ; S. C. Xiang ; R. B. Fu ; S. M. Hu ; Y. M. Li ; X. T. Wu |
| 刊名 | Chinese Journal of Structural Chemistry
 |
| 出版日期 | 2007 |
| 卷号 | 26期号:2页码:161-164 |
| 关键词 | hydrothermal synthesis huisgen 1 in situ 3-dipolar cycloaddition crystal structure copper ditetrazolate click chemistry approach coordination polymers tetrazole nitriles networks cyanides azides |
| ISSN号 | 0254-5861 |
| 中文摘要 | The hydrothermal reaction of 1,2-dicyanobenzene with NaN3 in the presence of CuCl2, 2,2'-bipyridine and H2O affords a novel dinuclear copper(II)-ditetrazolate, [Cu(bpy)(pdtz)](2) (Hpdtz = 5,5'-1,2-phenylene-ditetrazole, bpy = 2,2'-bipyridine). The pdtz ligand is generated in situ. through Sharpless 2+3 cycloaddition reaction. Its crystal structure was determined by single-crystal X-ray diffraction method. The crystal crystallizes in the monoclinic system, space group P2(1)/n with a = 8.2096(16), b = 18.580(4), c = 11.838(2) angstrom, beta = 103.12(3)degrees, V = 1758.5(6) angstrom(3), Z = 2, M-r = 863.83, D-c = 1.631 g/cm(3), F(000) = 876 and mu = 1.272 mm(-1). In this novel dinuclear structure, the pdtz ligand adopts a peculiar mu(2)-eta(1),eta(2) coordination mode. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6324]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | X. H. Huang,T. L. Sheng,S. C. Xiang,et al. Synthesis and structure of a dinuclear copper(II)-ditetrazolate involving in situ ligand synthesis[J]. Chinese Journal of Structural Chemistry,2007,26(2):161-164. |
| APA | X. H. Huang.,T. L. Sheng.,S. C. Xiang.,R. B. Fu.,S. M. Hu.,...&X. T. Wu.(2007).Synthesis and structure of a dinuclear copper(II)-ditetrazolate involving in situ ligand synthesis.Chinese Journal of Structural Chemistry,26(2),161-164. |
| MLA | X. H. Huang,et al."Synthesis and structure of a dinuclear copper(II)-ditetrazolate involving in situ ligand synthesis".Chinese Journal of Structural Chemistry 26.2(2007):161-164. |
入库方式： OAI收割
来源：福建物质结构研究所
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