Synthesis, structure and luminescence of a novel 2D cadmium coordination polymer with a ligand generated in situ
文献类型:期刊论文
作者 | X. H. Huang ; T. L. Sheng ; S. C. Xiang ; R. B. Fu ; S. M. Hu ; Y. M. Li ; X. T. Wu |
刊名 | Chinese Journal of Structural Chemistry
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出版日期 | 2007 |
卷号 | 26期号:3页码:333-337 |
关键词 | hydrothermal synthesis huisgen 1 in situ 3-dipolar cycloaddition crystal structure cadmium click chemistry approach tetrazolate complexes architectures frameworks cyanides azides |
ISSN号 | 0254-5861 |
中文摘要 | The hydrothermal reaction of 1,2-dicyanobenzene with NaN3 in the presence of Cd(NO3)(2) affords a novel 2D cadmium tetrazolyl-benzoate, {Cd(tzbz)(H2O)}(n) (H(2)tzbz is 2-(5-tetrazolyl)-benzoate). The tzbz ligand is generated in situ through the [2+3] Sharpless cycloaddition reaction and hydrolyzation. Its crystal structure was determined by single-crystal X-ray diffraction method. The crystal crystallizes in the orthorhombic system, space group Pbca with a = 9.6659(19), b = 7.6366(15), c = 25.964(5) angstrom, V = 1916.5(7) angstrom(3), Z = 8, M-r = 318.57, D-c = 2.208 g/cm(3), F(000) = 1232 and mu = 2.276 min(-1). The Cd(II) atom is coordinated by four tzbz ligands and one water molecule to form a severely distorted pentangle bipyramid. While each tzbz ligand connects to four Cd(II) atoms in a mu(4)-eta(1), eta(2), eta(1), eta(1), eta(1) coordination mode to construct a 2D architecture of the title complex. Additionally, the title complex exhibits strong fluorescence at room temperature in the solid state. |
语种 | 英语 |
公开日期 | 2013-04-01 |
源URL | [http://ir.fjirsm.ac.cn/handle/350002/6327] ![]() |
专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
推荐引用方式 GB/T 7714 | X. H. Huang,T. L. Sheng,S. C. Xiang,et al. Synthesis, structure and luminescence of a novel 2D cadmium coordination polymer with a ligand generated in situ[J]. Chinese Journal of Structural Chemistry,2007,26(3):333-337. |
APA | X. H. Huang.,T. L. Sheng.,S. C. Xiang.,R. B. Fu.,S. M. Hu.,...&X. T. Wu.(2007).Synthesis, structure and luminescence of a novel 2D cadmium coordination polymer with a ligand generated in situ.Chinese Journal of Structural Chemistry,26(3),333-337. |
MLA | X. H. Huang,et al."Synthesis, structure and luminescence of a novel 2D cadmium coordination polymer with a ligand generated in situ".Chinese Journal of Structural Chemistry 26.3(2007):333-337. |
入库方式: OAI收割
来源:福建物质结构研究所
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