Syntheses, crystal structures and magnetism of two new coordination polymers Ni(bix)(2)Cl-2 (n) and Co(bix)Cl-2 (n)
文献类型：期刊论文
| 作者 | Z. Hui ; S. W. Du |
| 刊名 | Chinese Journal of Structural Chemistry
 |
| 出版日期 | 2007 |
| 卷号 | 26期号:6页码:711-716 |
| 关键词 | bix 1 bix=1 magnetic property 4-bis(imidazol-1-ylmethyl)benzene 4-bis(imidazol-1-ylmethyl)benzene non-rigid ligand crystal structure pi-pi stacking building-blocks bix architectures framework networks ligands polyrotaxane |
| ISSN号 | 0254-5861 |
| 中文摘要 | The self-assembly reactions of (MCl2)-Cl-II (M = Ni, Co) with the flexible bix ligand [bix = 1,4-bis(imidazole-1-ylmethyl)benzene] yielded a 2D network [Ni-II(bix)(2)Cl-2](n) 1 and a 1D chain [Co-II(bix)Cl-2](n) 2. Their crystal structures have been determined by X-ray single-crystal diffraction analysis. Complex 1 characters a two-dimensional grid-type structure and crystallizes in monoclinic, space group P21/c with,a = 7.7231(7), b = 12.7787(9), c = 13.9374(13) angstrom, beta = 105.419(4)degrees, C28H28Cl2N8Ni, M-r = 606.19, Z = 2, V = 1326.0(2) angstrom(3), D-c = 1.518 g/cm(3), mu = 0.969 mm(-1), F(000) = 628, R = 0.0429 and wR 0.0783 for 2503 observed reflections (I > 2 sigma(I)). Compound 2 is a one-dimensional chain and crystallizes in orthorhombic, space group Pbca with a 11.3696(6), b = 10.2128(6), c = 14.4943(9) angstrom, C14H14Cl2CoN4, M-r = 368.12, Z = 4, V = 1683.01(17) angstrom(3), D-c = 1.453 g/cm(3), mu = 1.334 mm(-1), F(000) = 748, R = 0.0317 and wR = 0.0800 for 1778 observed reflections (I > 2 sigma(I)). Magnetic properties of the title complexes were also investigated. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6340]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | Z. Hui,S. W. Du. Syntheses, crystal structures and magnetism of two new coordination polymers Ni(bix)(2)Cl-2 (n) and Co(bix)Cl-2 (n)[J]. Chinese Journal of Structural Chemistry,2007,26(6):711-716. |
| APA | Z. Hui,&S. W. Du.(2007).Syntheses, crystal structures and magnetism of two new coordination polymers Ni(bix)(2)Cl-2 (n) and Co(bix)Cl-2 (n).Chinese Journal of Structural Chemistry,26(6),711-716. |
| MLA | Z. Hui,et al."Syntheses, crystal structures and magnetism of two new coordination polymers Ni(bix)(2)Cl-2 (n) and Co(bix)Cl-2 (n)".Chinese Journal of Structural Chemistry 26.6(2007):711-716. |
入库方式： OAI收割
来源：福建物质结构研究所
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