Synthesis, crystal structure and magnetic properties of an oxalate-bridged diiron(III) complex { Fe-III(salapn) (2)(C2O4)}
文献类型:期刊论文
作者 | H. P. Jia ; W. Li ; Z. F. Ju ; J. Zhang |
刊名 | Journal of Molecular Structure
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出版日期 | 2007-05 |
卷号 | 833期号:1-3页码:49-52 |
关键词 | diiron(III) complex bridging oxalate magnetic properties Schiff-base crystal structure single-molecule magnet ligands fefe mn |
ISSN号 | 0022-2860 |
中文摘要 | The oxalate-bridged Schiff-based complex {[Fe-III(salapn)](2)(C2O4)} (1) has been synthesized and characterized structurally (salapn = N,N'-bis(salicylaldehyde)-1,3-diaminopentane dianion). Each iron(III) ion is coordinated in slightly distorted octahedral geometry by two oxygen atoms and two nitrogen atoms from a salapn ligand, and two carboxylate oxygen atoms from an oxalate ligand. The [Fe(salapn)] moiety is linked by a bridging oxalate ligand to form a dimeric entity. The magnetic susceptibility study of 1 demonstrates the presence of antiferromagnetic interaction between two Fe(III) ions. (C) 2006 Elsevier B.V. All rights reserved. |
语种 | 英语 |
公开日期 | 2013-04-01 |
源URL | [http://ir.fjirsm.ac.cn/handle/350002/6351] ![]() |
专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
推荐引用方式 GB/T 7714 | H. P. Jia,W. Li,Z. F. Ju,et al. Synthesis, crystal structure and magnetic properties of an oxalate-bridged diiron(III) complex { Fe-III(salapn) (2)(C2O4)}[J]. Journal of Molecular Structure,2007,833(1-3):49-52. |
APA | H. P. Jia,W. Li,Z. F. Ju,&J. Zhang.(2007).Synthesis, crystal structure and magnetic properties of an oxalate-bridged diiron(III) complex { Fe-III(salapn) (2)(C2O4)}.Journal of Molecular Structure,833(1-3),49-52. |
MLA | H. P. Jia,et al."Synthesis, crystal structure and magnetic properties of an oxalate-bridged diiron(III) complex { Fe-III(salapn) (2)(C2O4)}".Journal of Molecular Structure 833.1-3(2007):49-52. |
入库方式: OAI收割
来源:福建物质结构研究所
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