Ni-3(Mo2O8)(XO3) (X = Se, Te): The first nickel selenite- and tellurite-containing Mo-4 clusters
文献类型：期刊论文
| 作者 | H. L. Jiang ; Z. Xie ; J. G. Mao |
| 刊名 | Inorganic Chemistry
 |
| 出版日期 | 2007-08 |
| 卷号 | 46期号:16页码:6495-6501 |
| 关键词 | bond-valence parameters tetranuclear core crystal-structure oxides complexes system family anions ta5+ nb5+ |
| ISSN号 | 0020-1669 |
| 中文摘要 | Two new nickel(II) molybdenum(VI) selenium(IV) and tellurium(IV) oxides generally formulated as Ni-3(Mo2O8)(XO3) (X = Se, Te) have been synthesized by solid-state reactions of NiO, MoO3, and SeO2 (or TeO2). Both compounds feature 3D network structures built of [Mo4O16](8-) tetranuclear cluster units and 2D nickel(II) selenite or tellurite layers. The nickel(II) selenite layer in Ni-3(Mo2O8)(SeO3) is formed by [Ni6O22](32-) hexanuclear clusters interconnected by selenite groups whereas the thick nickel(II) tellurite layer in Ni-3(Mo2O8)(TeO3) is constructed by corrugated nickel(II) oxide chains bridged by the tellurite groups. The results of magnetic property measurements indicate that there are considerable ferromagnetic interactions between nickel(II) centers in both compounds. Their optical properties and band structures have been also studied. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6363]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | H. L. Jiang,Z. Xie,J. G. Mao. Ni-3(Mo2O8)(XO3) (X = Se, Te): The first nickel selenite- and tellurite-containing Mo-4 clusters[J]. Inorganic Chemistry,2007,46(16):6495-6501. |
| APA | H. L. Jiang,Z. Xie,&J. G. Mao.(2007).Ni-3(Mo2O8)(XO3) (X = Se, Te): The first nickel selenite- and tellurite-containing Mo-4 clusters.Inorganic Chemistry,46(16),6495-6501. |
| MLA | H. L. Jiang,et al."Ni-3(Mo2O8)(XO3) (X = Se, Te): The first nickel selenite- and tellurite-containing Mo-4 clusters".Inorganic Chemistry 46.16(2007):6495-6501. |
入库方式： OAI收割
来源：福建物质结构研究所
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