Syntheses, crystal structures, thermal stabilities, and magnetic and luminescent properties of 3D heterometal phosphonates: NaM O3PCH(OH)CO2 (M = Mn, Fe, Co, Zn)
文献类型：期刊论文
| 作者 | Z. Z. Lai ; R. B. Fu ; S. M. Hu ; X. T. Wu |
| 刊名 | European Journal of Inorganic Chemistry
 |
| 出版日期 | 2007-12 |
| 期号 | 34页码:5439-5446 |
| 关键词 | crystal structure phosphorus luminescence magnetism thermal stability open-framework metal phosphonates coordination polymers thin-films photoluminescence diphosphonates chemistry channels aluminum chains |
| ISSN号 | 1434-1948 |
| 中文摘要 | Four heterometal 2-hydroxyl(phosphono)carboxylates, NaM[O3PCH(OH)CO2] [M = Mn (1), Fe (2), Co (3), Zn (4)], were synthesized hydrothermally. Single-crystal X-ray diffraction data reveal that they are isostructural and crystallize in the orthorhombic space group Pbca (No. 61) with a = 10.1365(16)-10.4557(5) angstrom, b = 9.6890(9)-9.8265(4) angstrom, c = 10.7942(19)-10.9353(1) angstrom, V= 1060.2(3)-1123.22(7) angstrom(3), and Z = 8. Each [MO6] (M = Mn, Fe, Co, Zn) octahedron contacts three neighboring [NaO5] pyramids through two edges and one corner to form a Na/MO layer. The layers are further connected by O3PCH(OH)CO23- groups into an interesting 3D heterometallic framework. Thermogravimetric and powder X-ray diffraction analysis indicate that solids 1-4 are thermally stable up to 350, 250, 340, and 350 degrees C, respectively. Magnetic measurements show the presence of antiferromagnetic interaction for M-II ions (M = Mn, Fe, Cc) in compounds 1-3. These solids exhibit bright cyan (for 1, 2, and 4) or purple (for 3) luminescence after induced by fluorescent whitener, and the luminescence can be irreversibly transformed into bright yellow (for 1 and 4) or red (for 3) simply by annealing treatment at 300 degrees C. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007) |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6366]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | Z. Z. Lai,R. B. Fu,S. M. Hu,et al. Syntheses, crystal structures, thermal stabilities, and magnetic and luminescent properties of 3D heterometal phosphonates: NaM O3PCH(OH)CO2 (M = Mn, Fe, Co, Zn)[J]. European Journal of Inorganic Chemistry,2007(34):5439-5446. |
| APA | Z. Z. Lai,R. B. Fu,S. M. Hu,&X. T. Wu.(2007).Syntheses, crystal structures, thermal stabilities, and magnetic and luminescent properties of 3D heterometal phosphonates: NaM O3PCH(OH)CO2 (M = Mn, Fe, Co, Zn).European Journal of Inorganic Chemistry(34),5439-5446. |
| MLA | Z. Z. Lai,et al."Syntheses, crystal structures, thermal stabilities, and magnetic and luminescent properties of 3D heterometal phosphonates: NaM O3PCH(OH)CO2 (M = Mn, Fe, Co, Zn)".European Journal of Inorganic Chemistry .34(2007):5439-5446. |
入库方式： OAI收割
来源：福建物质结构研究所
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