Synthesis, crystal structure and band structure of EU3Sn5 with arachno-type zintl anions
文献类型：期刊论文
| 作者 | X. W. Lei ; J. G. Mao |
| 刊名 | Chinese Journal of Structural Chemistry
 |
| 出版日期 | 2007 |
| 卷号 | 26期号:12页码:1403-1408 |
| 关键词 | intermetallic stannide crystal structure band structure intermetallic compounds phase-diagram sn system clathrate structure solid-state tin clusters patterns metals chains |
| ISSN号 | 0254-5861 |
| 中文摘要 | A new polar intermetallic compound, Eu3Sn5, has been synthesized by solid-state reaction of the corresponding pure elements in a stoichiometric ratio in a welded tantalum tube at high temperature. Its crystal structure was established by single-crystal X-ray diffraction. EU3Sn5 crystallizes in orthorhombic, space group Cmcm with a = 10.466(11), b = 8.445(8), c = 10.662(12) angstrom, V = 942.4(17) angstrom(3), Z = 4, M-r = 1049.33, D-c = 7.396 g/cm(3), mu = 32.578 mm(-1), F(000) = 1756, the final R = 0.0236 and wR = 0.0472 for 535 observed reflections with I > 2 sigma(I). Its structure belongs to the modified PU3Pd5 type. It is isostructural with Sr3Sn5 and Ba3Sn5, featuring [Sn-5] square pyramidal clusters described as "arachno" according to the Wade-Mingos electron counting rules. The europium. cations are located at the voids between the square pyramidal clusters. Results of the extended Huckel band structure calculations indicate that EU3Sn5 is metallic. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6370]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | X. W. Lei,J. G. Mao. Synthesis, crystal structure and band structure of EU3Sn5 with arachno-type zintl anions[J]. Chinese Journal of Structural Chemistry,2007,26(12):1403-1408. |
| APA | X. W. Lei,&J. G. Mao.(2007).Synthesis, crystal structure and band structure of EU3Sn5 with arachno-type zintl anions.Chinese Journal of Structural Chemistry,26(12),1403-1408. |
| MLA | X. W. Lei,et al."Synthesis, crystal structure and band structure of EU3Sn5 with arachno-type zintl anions".Chinese Journal of Structural Chemistry 26.12(2007):1403-1408. |
入库方式： OAI收割
来源：福建物质结构研究所
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