Two novel grid networks based on Keggin-type polyoxometalate clusters assembled through weak Cu center dot center dot center dot O interactions
文献类型：期刊论文
| 作者 | T. H. Li ; J. Lu ; S. Y. Gao ; R. Cao |
| 刊名 | Inorganic Chemistry Communications
 |
| 出版日期 | 2007-05 |
| 卷号 | 10期号:5页码:551-554 |
| 关键词 | grid networks polyoxometalate Keggin weak interaction transition-metal-complexes coordination polymers structural-characterization hydrothermal synthesis crystal-structures ligands architectures chemistry catalysis anions |
| ISSN号 | 1387-7003 |
| 中文摘要 | Two novel grid networks based on Keggin-type polyoxoanion, formulated [Cu(2,2'-bipy)(2)](HPMo12O40)-H2O (1) and [Cu(2,2'bipy)(2)](HPW12O40) -H2O (2) have been synthesized hydrothermally and characterized by elemental analyses, IR, EPR and X-ray single crystal diffraction. 1 is a 2D grid network built by the interconnection of bisupporting polyoxoanion clusters assembled through weak (CuO)-O-... interactions. The EPR spectrum of I indicates that its unpaired electrons are placed in d(x2-y)(2) orbital of the ground state of Cu(11). Compound 2 is isostructural with compound 1. (c) 2007 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6409]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | T. H. Li,J. Lu,S. Y. Gao,et al. Two novel grid networks based on Keggin-type polyoxometalate clusters assembled through weak Cu center dot center dot center dot O interactions[J]. Inorganic Chemistry Communications,2007,10(5):551-554. |
| APA | T. H. Li,J. Lu,S. Y. Gao,&R. Cao.(2007).Two novel grid networks based on Keggin-type polyoxometalate clusters assembled through weak Cu center dot center dot center dot O interactions.Inorganic Chemistry Communications,10(5),551-554. |
| MLA | T. H. Li,et al."Two novel grid networks based on Keggin-type polyoxometalate clusters assembled through weak Cu center dot center dot center dot O interactions".Inorganic Chemistry Communications 10.5(2007):551-554. |
入库方式： OAI收割
来源：福建物质结构研究所
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