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Chinese Academy of Sciences Institutional Repositories Grid
Two Cu(II) double betaine coordination polymers with different metal-organic frameworks

文献类型:期刊论文

作者Y. Li ; G. Q. Li ; W. Q. Zou ; F. K. Zheng ; J. P. Zou ; G. C. Guo ; C. Z. Lu ; J. S. Huang
刊名Journal of Molecular Structure
出版日期2007-06
卷号837期号:1-3页码:231-236
关键词double betaine polymer crystal structure copper complex flexible double betaines dicarboxylate-like ligands crystal-structures structural-characterization building-blocks complexes networks lanthanum(iii) architectures copper(ii)
ISSN号0022-2860
中文摘要Two new Cu(II) coordination polymers with double betaine ligands have been prepared, and their structures have been characterized by single-crystal X-ray diffraction techniques. The structure of [Cu(L-1)(2)](Clo(4))(2)center dot 2H(2)O 1 (L-1 = 1,3-bis(pyridinio-4-carboxylato)-propane) contains 1-D cationic chains, in which the adjacent Cu(II) atoms are doubly bridged by L-1 ligands in the syn-syn bis-monodentate mode. In [Cu(L-2)(2)](Clo(4))(2)center dot 4H(2)O 2 (L-2 = 1,4-bis(pyridinio-4-carboxylato)-1,4-dimenthyl benzene), the Cu(II) atoms are joined by the L-2 ligands in the same coordination mode as 1 in two directions to form a 2-D grid-like framework. The crystal packing in 1 and 2 is controlled mainly by face-to-face pi-pi stacking interactions between pyridine rings. The thermal stability of 1 has also been investigated. (c) 2006 Elsevier B.V. All rights reserved.
语种英语
公开日期2013-04-01
源URL[http://ir.fjirsm.ac.cn/handle/350002/6429]  
专题福建物质结构研究所_中科院福建物质结构研究所_期刊论文
推荐引用方式
GB/T 7714
Y. Li,G. Q. Li,W. Q. Zou,et al. Two Cu(II) double betaine coordination polymers with different metal-organic frameworks[J]. Journal of Molecular Structure,2007,837(1-3):231-236.
APA Y. Li.,G. Q. Li.,W. Q. Zou.,F. K. Zheng.,J. P. Zou.,...&J. S. Huang.(2007).Two Cu(II) double betaine coordination polymers with different metal-organic frameworks.Journal of Molecular Structure,837(1-3),231-236.
MLA Y. Li,et al."Two Cu(II) double betaine coordination polymers with different metal-organic frameworks".Journal of Molecular Structure 837.1-3(2007):231-236.

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来源:福建物质结构研究所

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