A unique 3-D 3d-4f heterometallic coordination polymer with double betaine ligand: Crystal structure and magnetic properties
文献类型：期刊论文
| 作者 | Y. Li ; F. K. Zheng ; J. P. Zou ; W. Q. Zou ; H. W. Ma ; G. C. Guo ; C. Z. Lu ; J. S. Huang |
| 刊名 | Inorganic Chemistry Communications
 |
| 出版日期 | 2007-07 |
| 卷号 | 10期号:7页码:787-791 |
| 关键词 | coordination polymer carboxylate ligands heterometallic complexes magnetic properties flexible double betaines dicarboxylate-like ligands gd-iii molecular-structure building-blocks complexes series ln gadolinium(iii) copper |
| ISSN号 | 1387-7003 |
| 中文摘要 | A unique 3d-4f heterometallic coordination polymer with double betaine ligand, [GdCu2(L-1)(4)(H2O2)(2)](ClO4)(7) center dot 6H(2)O 1 (L-1 = 1,3-bis(pyridinio-4-carboxylato)-propane), has been synthesized by the self-assembly of Cu(ClO4)(2) and Gd(ClO4)(3) with flexible double betaine ligand L-1, and structurally characterized by single-crystal X-ray diffraction. The structure of 1 can be regarded as being constructed by the cross-linkage of the vertex-sharing double-paddle-wheel-like trinuclear [Cu(COO)(4)Gd(COO)(4)Cu] units and L-1 ligands to produce an interesting cationic NaCl-like framework with a 4(12)6(3) topology, which is counter-balanced by the perchlorate ions located in the interspaces of the framework. Variable-temperature magnetic susceptibilities of 1 show there is no magnetic interaction between the Cu(II) and Gd(III) ions. (c) 2007 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6430]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | Y. Li,F. K. Zheng,J. P. Zou,et al. A unique 3-D 3d-4f heterometallic coordination polymer with double betaine ligand: Crystal structure and magnetic properties[J]. Inorganic Chemistry Communications,2007,10(7):787-791. |
| APA | Y. Li.,F. K. Zheng.,J. P. Zou.,W. Q. Zou.,H. W. Ma.,...&J. S. Huang.(2007).A unique 3-D 3d-4f heterometallic coordination polymer with double betaine ligand: Crystal structure and magnetic properties.Inorganic Chemistry Communications,10(7),787-791. |
| MLA | Y. Li,et al."A unique 3-D 3d-4f heterometallic coordination polymer with double betaine ligand: Crystal structure and magnetic properties".Inorganic Chemistry Communications 10.7(2007):787-791. |
入库方式： OAI收割
来源：福建物质结构研究所
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