Two novel anion-directed Cu(II) double betaine coordination polymers with different open frameworks: Inorganic chains Cu-3( mu(3)-OH)(2)(mu(2)-H2O)(2) (n) as secondary building units with unusual chair-like Cu3O4 cores
文献类型：期刊论文
| 作者 | Y. Li ; J. P. Zou ; W. Q. Zou ; F. K. Zheng ; G. C. Guo ; C. Z. Lu ; J. S. Huang |
| 刊名 | Inorganic Chemistry Communications
 |
| 出版日期 | 2007-09 |
| 卷号 | 10期号:9页码:1026-1030 |
| 关键词 | anion template coordination polymers crystal structure double betaine inorganic chain flexible double betaines dicarboxylate-like ligands metal-organic frameworks structural diversity magnetic-properties copper(ii) complex crystal-structures network solids channels design |
| ISSN号 | 1387-7003 |
| 中文摘要 | The reaction of double betaine ligand L-1(L-1 = 1,3-bis(pyridinio-4-carboxylato)-propane) with CU(ClO4)(2) and Cu(NO3)(2), respectively, afforded two novel anion-directed coordination polymers with different open frameworks. The structure Of [CU3(L-1)(2)(OH)(2)(H2O)(2)](ClO4)(4)center dot 2H(2)O 1 is a unique 3-D open-framework with large S-shape channels, while [CU3(L2(1))(2)(OH)(2)(H2O)(2)](NO3)(4)-2H(2)O 2 has a 2-D tubular structure. There exist inorganic copper-oxo chains [CU3(L-1)(2)-(OH)(2)(H2O)(2)](n) in both 1 and 2 as secondary building units, in which the [Cu3O4] cores exhibit a rarely observed chair-like configuration. The anion template of ClO4- and NO3-, and labile coordination orientation of L-1 ligand prompt the formation of different polymeric networks in 1 and 2. (c) 2007 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6433]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | Y. Li,J. P. Zou,W. Q. Zou,et al. Two novel anion-directed Cu(II) double betaine coordination polymers with different open frameworks: Inorganic chains Cu-3( mu(3)-OH)(2)(mu(2)-H2O)(2) (n) as secondary building units with unusual chair-like Cu3O4 cores[J]. Inorganic Chemistry Communications,2007,10(9):1026-1030. |
| APA | Y. Li.,J. P. Zou.,W. Q. Zou.,F. K. Zheng.,G. C. Guo.,...&J. S. Huang.(2007).Two novel anion-directed Cu(II) double betaine coordination polymers with different open frameworks: Inorganic chains Cu-3( mu(3)-OH)(2)(mu(2)-H2O)(2) (n) as secondary building units with unusual chair-like Cu3O4 cores.Inorganic Chemistry Communications,10(9),1026-1030. |
| MLA | Y. Li,et al."Two novel anion-directed Cu(II) double betaine coordination polymers with different open frameworks: Inorganic chains Cu-3( mu(3)-OH)(2)(mu(2)-H2O)(2) (n) as secondary building units with unusual chair-like Cu3O4 cores".Inorganic Chemistry Communications 10.9(2007):1026-1030. |
入库方式： OAI收割
来源：福建物质结构研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。