Synthesis and crystal structures of three novel coordination polymers generated from AgCN and AgSCN with flexible N-donor ligands
文献类型：期刊论文
| 作者 | H. D. Lin ; Z. H. Li ; J. R. Li ; S. W. Du |
| 刊名 | Polyhedron
 |
| 出版日期 | 2007-01 |
| 卷号 | 26期号:1页码:107-114 |
| 关键词 | coordination polymers 1 cyanide-bridging 4-bis(imidazol-1-ylmethyl)benzene triply-bridged SCN ligand photoluminescent property interpenetration flexible N-donor ligands metal-organic framework building-blocks silver(i) thiocyanate 1/2 adducts complexes polyrotaxane network cyanide salts |
| ISSN号 | 0277-5387 |
| 中文摘要 | The solvothermal reactions of AgX (X=CN, SCN) with mbix [mbix=1,3-bis(imidazole-1-yl-methyl)benzene] or bix [bix=1, 4bis(imidazole-1-yl-methyl)benzene] afforded the polymers [AgCN(mbix)](n) (1), [(AgCN)(4)(bix)(2)](n) (2) and [(AgSCN)(2)(mbix)](n) (3). They were all characterized by infrared spectroscopy, elemental analysis and X-ray single-crystal analysis. The structure of 1 contains a 3-fold-interpenetrated 2D network, while that of 2 exhibits 2-fold parallel interpenetration. There is no interpenetration observed in 3. Compounds 2 and 3 show 3D supramolecular structures built from 2D networks through weak pi center dot center dot center dot pi interactions. The photoluminescent properties of the present compounds were also investigated. (c) 2006 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6442]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | H. D. Lin,Z. H. Li,J. R. Li,et al. Synthesis and crystal structures of three novel coordination polymers generated from AgCN and AgSCN with flexible N-donor ligands[J]. Polyhedron,2007,26(1):107-114. |
| APA | H. D. Lin,Z. H. Li,J. R. Li,&S. W. Du.(2007).Synthesis and crystal structures of three novel coordination polymers generated from AgCN and AgSCN with flexible N-donor ligands.Polyhedron,26(1),107-114. |
| MLA | H. D. Lin,et al."Synthesis and crystal structures of three novel coordination polymers generated from AgCN and AgSCN with flexible N-donor ligands".Polyhedron 26.1(2007):107-114. |
入库方式： OAI收割
来源：福建物质结构研究所
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