Investigation on crystallization kinetics and microstructure of novel transparent glass ceramics containing Nd : NaYF4 nano-crystals
文献类型：期刊论文
| 作者 | F. Liu ; Y. S. Wang ; D. Q. Chen ; Y. L. Yu |
| 刊名 | Materials Science and Engineering B-Solid State Materials for Advanced Technology
 |
| 出版日期 | 2007-01 |
| 卷号 | 136期号:2-3页码:106-110 |
| 关键词 | oxyfluoride glass ceramic NaYF4 crystallization kinetics up-conversion luminescence sodium yttrium fluoride phosphors system green er3+ size |
| ISSN号 | 0921-5107 |
| 中文摘要 | Nd3+-doped transparent oxyfluoride glass ceramics containing NaYF4 nano-crystals were prepared by melt-quenching and subsequent heating, and the crystallization kinetics of NaYF4 from the glass was investigated for the first time. Transmission electron microscopy (TEM) and X-ray diffraction (XRD) investigation reveal that spherical NaYF4 nano-crystals are distributed homogeneously among the glassy matrix for the sample doped with 1% Nd3+ and heated at 620 degrees C for 2 h. The kinetics study indicates that the mean apparent activation energy Ea and Avrami exponent n of the crystallization are 315 kJ/mol and 1.77, respectively, suggesting the crystallization being a diffusion-controlled growth process of particles with decreasing nucleation rate. The XRD data demonstrate a durative lattice expansion of cubic NaYF4 with the increasing of Nd3+ content in the sample, indicating the incorporation of Nd3+, into the crystallites which is further verified by the energy dispersive X-ray spectroscopy (EDS) and absorption spectra analyses of Nd3+, in glass and glass ceramic. (c) 2006 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6470]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | F. Liu,Y. S. Wang,D. Q. Chen,et al. Investigation on crystallization kinetics and microstructure of novel transparent glass ceramics containing Nd : NaYF4 nano-crystals[J]. Materials Science and Engineering B-Solid State Materials for Advanced Technology,2007,136(2-3):106-110. |
| APA | F. Liu,Y. S. Wang,D. Q. Chen,&Y. L. Yu.(2007).Investigation on crystallization kinetics and microstructure of novel transparent glass ceramics containing Nd : NaYF4 nano-crystals.Materials Science and Engineering B-Solid State Materials for Advanced Technology,136(2-3),106-110. |
| MLA | F. Liu,et al."Investigation on crystallization kinetics and microstructure of novel transparent glass ceramics containing Nd : NaYF4 nano-crystals".Materials Science and Engineering B-Solid State Materials for Advanced Technology 136.2-3(2007):106-110. |
入库方式： OAI收割
来源：福建物质结构研究所
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