Two organically templated niobium and zinconiobium fluorophosphates: Low temperature hydrothermal syntheses of NbOF(PO4)(2)(C2H10N2)(2) and Zn-3(NbOF)(PO4)(4)(C2H10N2)(2)
文献类型：期刊论文
| 作者 | G. Z. Liu ; S. T. Zheng ; G. Y. Yang |
| 刊名 | Inorganic Chemistry
 |
| 出版日期 | 2007-01 |
| 卷号 | 46期号:1页码:231-237 |
| 关键词 | one-dimensional aluminophosphate oxide fluoride anions of-center distortions crystal-structure composition space metal phosphates tunnel structure porous materials alp2o83-chains framework |
| ISSN号 | 0020-1669 |
| 中文摘要 | Two new niobium and zinconiobium fluorophosphates, NbOF(PO4)(2)(C2H10N2)(2) (1) and Zn-3(NbOF)(PO4)(4)-(C2H10N2)(2) (2), have been prepared under hydrothermal conditions using ethylenediamine as a template. The structures were determined by single crystal diffraction to be triclinic, space group P(1) over bar (No. 2), a = 8.1075 (6) angstrom, b = 9.8961 (7) angstrom, c = 10.1420(8) angstrom, alpha = 111.655(1)degrees, beta = 111.51(1)degrees, gamma = 93.206(1)degrees, V = 686.19(9) angstrom(3), and Z = 2 for 1 and orthorhombic, space group Fddd (No. 70), a = 9.1928(2) A, b = 14.2090(10) angstrom, c = 32.2971 (6) angstrom, V = 4218.66(12) angstrom(3), and Z = 8 for 2, respectively. Compound 1 is an infinite linear chain consisting of corner-sharing [Nb2P2] 4-MRs bridged at the Nb centers with organic amines situated between chains, and compound 2, containing the chains similar to that in 1, forms a zeotype framework with organic amines situated in the gismondine-type [4(6)8(4)] cavities. The topology of 2 was previously unknown with vertex symbol 4.4.4.4.8.8 (vertex 1), 4.4.4.8(2).8.8 (vertex 2), 4.4.8.8.8(2).8(2) (vertex 3), and 4.4.4.8(2) (.)8.8 (vertex 4). The topological relationships between the 4-connected network of 2 and several reported (3,4)-connected networks were discussed. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6477]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | G. Z. Liu,S. T. Zheng,G. Y. Yang. Two organically templated niobium and zinconiobium fluorophosphates: Low temperature hydrothermal syntheses of NbOF(PO4)(2)(C2H10N2)(2) and Zn-3(NbOF)(PO4)(4)(C2H10N2)(2)[J]. Inorganic Chemistry,2007,46(1):231-237. |
| APA | G. Z. Liu,S. T. Zheng,&G. Y. Yang.(2007).Two organically templated niobium and zinconiobium fluorophosphates: Low temperature hydrothermal syntheses of NbOF(PO4)(2)(C2H10N2)(2) and Zn-3(NbOF)(PO4)(4)(C2H10N2)(2).Inorganic Chemistry,46(1),231-237. |
| MLA | G. Z. Liu,et al."Two organically templated niobium and zinconiobium fluorophosphates: Low temperature hydrothermal syntheses of NbOF(PO4)(2)(C2H10N2)(2) and Zn-3(NbOF)(PO4)(4)(C2H10N2)(2)".Inorganic Chemistry 46.1(2007):231-237. |
入库方式： OAI收割
来源：福建物质结构研究所
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