Assembly of two novel three-dimensional networks driven by Alkali metals with an irreversible structural conversion
文献类型：期刊论文
| 作者 | H. Lu ; F. Li ; D. Q. Yuan ; R. Cao |
| 刊名 | Polyhedron
 |
| 出版日期 | 2007-08 |
| 卷号 | 26期号:13页码:2979-2986 |
| 关键词 | copper alkali metal metal-organic framework heterometallic three-dimensional heterometallic coordination polymers magnetic-properties organic framework building-blocks adsorption properties copper-complexes 3d ligands design exchange |
| ISSN号 | 0277-5387 |
| 中文摘要 | Two novel three-dimensional (3-D) heterometallic frameworks containing dinuclear p-block metal-oxygen clusters, formulated as [Na-2,(H2O)(3)Cu-2,(H2O)6(SiP)21 center dot H,O I and [K,(H2O)(2)CU2(H2O)5(SiP)21 center dot H2O 2 (Sip(3-) = 5-sulfoisophthalic anion), have been synthesized at room temperature. Single-crystal X-ray diffraction revealed that similar structural motifs (one-dimensional zigzag chain built by copper atoms and sip(3-) ligands, and dinuclear p-block metal-oxygen clusters) can be found within their crystal structures. Compound I shows an interesting 3-D structure constructed from copper-sip chains interconnected by two kinds of dinuclear sodium-oxygen clusters adopting 4- and 6-connected fashions. Compound 2 displays a 3-D framework formed by cross-linking copper-sip chains via 6-connected dinuclear potassium-oxygen clusters. Interestingly, an irreversible structural conversion from 1 to 2 was observed. (c) 2007 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6506]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | H. Lu,F. Li,D. Q. Yuan,et al. Assembly of two novel three-dimensional networks driven by Alkali metals with an irreversible structural conversion[J]. Polyhedron,2007,26(13):2979-2986. |
| APA | H. Lu,F. Li,D. Q. Yuan,&R. Cao.(2007).Assembly of two novel three-dimensional networks driven by Alkali metals with an irreversible structural conversion.Polyhedron,26(13),2979-2986. |
| MLA | H. Lu,et al."Assembly of two novel three-dimensional networks driven by Alkali metals with an irreversible structural conversion".Polyhedron 26.13(2007):2979-2986. |
入库方式： OAI收割
来源：福建物质结构研究所
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