Synthesis, crystal structure and luminescent properties of TbCu(TeO3)(2)Cl
文献类型：期刊论文
| 作者 | E. Ma ; H. L. Jiang |
| 刊名 | Chinese Journal of Structural Chemistry
 |
| 出版日期 | 2007 |
| 卷号 | 26期号:10页码:1159-1164 |
| 关键词 | terbium(III) tellurium(IV) oxychloride solid-state reaction crystal structure luminescence oxotellurate(iv) lanthanide glass |
| ISSN号 | 0254-5861 |
| 中文摘要 | TbCu(TeO3)(2)Cl was obtained in high yield from high temperature solid-state reaction of Tb4O7, CuO, CuCl2, and TeO2 in a 1:2:2:8 molar ratio at 710 degrees C in an evacuated quartz tube. Its structure was established by single crystal X-ray diffraction. The title compound crystallizes in monoclinic, space group P2(1)/c, with a = 5.409(2), b = 14.994(6), c = 9.183(4) angstrom, beta = 98.884(5)degrees, V = 735.8(5) angstrom and Z = 4. TbCu(TeO3)(2)Cl is isostructural with LnCu(TeO3)(2)X (Ln = Dy X = Cl; Ln = Er, X = Cl, Br). Its structure features a three-dimensional (3D) network built from Tb(III) and Cu(II) ions interconnected by tellurite and chloride anions; the chloride anion and the lone-pair elelctrons of the tellurium(IV) ions are oriented toward the cavities of the tunnels in the network. Solid-state luminescent spectrum of TbCu(TeO3)(2) shows a strong emission band at 545 nm with a luminescent life of 291 mu s. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6523]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | E. Ma,H. L. Jiang. Synthesis, crystal structure and luminescent properties of TbCu(TeO3)(2)Cl[J]. Chinese Journal of Structural Chemistry,2007,26(10):1159-1164. |
| APA | E. Ma,&H. L. Jiang.(2007).Synthesis, crystal structure and luminescent properties of TbCu(TeO3)(2)Cl.Chinese Journal of Structural Chemistry,26(10),1159-1164. |
| MLA | E. Ma,et al."Synthesis, crystal structure and luminescent properties of TbCu(TeO3)(2)Cl".Chinese Journal of Structural Chemistry 26.10(2007):1159-1164. |
入库方式： OAI收割
来源：福建物质结构研究所
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