Three-dimensional 3d-4f polymers containing heterometallic rings: Syntheses, structures, and magnetic properties
文献类型：期刊论文
| 作者 | Y. Ouyang ; W. Zhang ; N. Xu ; G. F. Xu ; D. Z. Liao ; K. Yoshimura ; S. P. Yan ; P. Cheng |
| 刊名 | Inorganic Chemistry
 |
| 出版日期 | 2007-10 |
| 卷号 | 46期号:21页码:8454-8456 |
| 关键词 | crystal-structure triethylenetetraaminehexaacetic acid coordination polymers absorption-spectroscopy neodymium(iii) complex optical spectroscopy extended arrays metal complexes ln lanthanide |
| ISSN号 | 0020-1669 |
| 中文摘要 | Two novel three-dimensional (3D) 3d-4f mixed complexes [Ln(H2O)(4)][Ni(2)TTHA(SCN)(2)]center dot H3O+ [Ln = Pr (1), Ce (2); H(6)TTHA = triethylenetetraaminehexaacetic acid], based on ' the building blocks of [Ni(2)TTHA(SCN)(2)](4-), were synthesized and characterized by X-ray crystal diffraction and magnetic properties. The single-crystal structures show that these complexes form a 3D framework, comprised of an unusual infinite one-dimensional chain based on heterometallic Ln(2)Ni(2) rings. The temperature-dependent magnetic susceptibilities were analyzed by an approximate model, leading to g = 2.06. Delta = 2.83, zJ' = -0.6 cm(-1) for complex 1 and g = 2.07, Delta = 1.00, zJ' = -0.5 cm(-1) for complex 2. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6545]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | Y. Ouyang,W. Zhang,N. Xu,et al. Three-dimensional 3d-4f polymers containing heterometallic rings: Syntheses, structures, and magnetic properties[J]. Inorganic Chemistry,2007,46(21):8454-8456. |
| APA | Y. Ouyang.,W. Zhang.,N. Xu.,G. F. Xu.,D. Z. Liao.,...&P. Cheng.(2007).Three-dimensional 3d-4f polymers containing heterometallic rings: Syntheses, structures, and magnetic properties.Inorganic Chemistry,46(21),8454-8456. |
| MLA | Y. Ouyang,et al."Three-dimensional 3d-4f polymers containing heterometallic rings: Syntheses, structures, and magnetic properties".Inorganic Chemistry 46.21(2007):8454-8456. |
入库方式： OAI收割
来源：福建物质结构研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。